Research

• Mars with engineered aerosol (Mars terraforming).

• Why did Mars' surface become uninhabitable?

• Which exoplanets have atmospheres, and why?

Papers (UChicago Planetary Geoscientists / advisees in bold)

• Ansari, Kite, Ramirez, Steele, and Mohseni, Feasibility of keeping Mars warm with nanoparticles, Science Advances, 2024. [ More] [open access] [news coverage in Science] [The Economist]
  
  One-third of Mars' surface has shallow-buried H2O, but it is currently too cold for use by life. Proposals to warm Mars using greenhouse gases require a large mass of ingredients that are rare on Mars' surface. However, we show here that artificial aerosols made from materials that are readily available at Mars - for example, conductive nanorods that are ~9 microns long - could warm Mars >5x10^3 times more effectively than the best gases. Such nanoparticles forward-scatter sunlight and efficiently block upwelling thermal infrared. Similar to the natural dust of Mars, they are swept high into Mars' atmosphere, allowing delivery from the near-surface. For a particle lifetime of 10 years, two climate models indicate that sustained release at 30 liters/sec would globally warm Mars by >~30 K and start to melt the ice. Therefore, if nanoparticles can be made at scale on (or delivered to) Mars, then the barrier to warming of Mars appears to not be as high as previously thought.
  
  
• DeBenedectis, Kite, Wordsworth, Lanza, Cockell, Silver, Ramirez, Cumbers, Mohseni, Mason, Fischer, and McKay, The case for Mars terraforming research, in review. [ More]
  
  Exploration of Mars is motivated by scientific, societal, and engineering goals, and the centuries-old dream that people could one day live there. Missions to date reveal a hostile surface environment, featuring a deadly triple cocktail of extreme cold, high surface UV fluxes, and lack of sustained liquid water. Despite this harshness, advocacy for large-scale Mars settlement has continued for decades, but is making Mars' surface hospitable to life possible and feasible? Proposed motivations for terraforming are diverse. Carl Sagan once wrote, "If we do not destroy ourselves, we will one day venture to the stars." Since Sagan's time we have confirmed that Mars was once habitable but suffered a global climate catastrophe, so some view Mars as an environmental restoration challenge. Some argue that a hospitable Mars is essential to achieve self-sufficiency, surpassing the limitations of isolated outposts. Others are motivated by the scientific desire to learn about the universe, as the realization of humanity's dreams to explore the universe is assisted by expanded human presence. Contemplating building a climate and ecosystem beyond Earth highlights gaps in our fundamental knowledge of these systems. Ongoing developments in three key areas have returned terraforming to the martian research agenda ...
  
  
• Burtt, Stern, Webster, Franz, Sutter, Thorpe, Kite, Eigenbrode, Pavlov, House, Tutolo, Des Marais, Rampe, McAdam, and Malespin, Highly enriched carbon and oxygen isotopes in carbonate-derived CO₂ at Gale Crater, Mars, Proceedings of the National Academy of Sciences, 2024. [htm] [ More]
  
  Carbonate minerals are of particular interest in paleoenvironmental research as they are an integral part of the carbon and water cycles, both of which are relevant to habitability. Given that these cycles are less constrained on Mars than they are on Earth, the identification of carbonates has been a point of emphasis for rover missions. Here, we present carbon (Δ13C) and oxygen (Δ18O) isotope data from four carbonates encountered by the Curiosity rover within the Gale crater. The carbon isotope values range from 72±2‰ to 110±3‰ Vienna Pee Dee Belemnite while the oxygen isotope values span from 59±4‰ to 91±4‰ Vienna Standard Mean Ocean Water (1 SE uncertainties). Notably, these values are isotopically heavy (13C- and 18O-enriched) relative to nearly every other Martian material. The extreme isotopic difference between the carbonates and other carbon- and oxygen-rich reservoirs on Mars cannot be reconciled by standard equilibrium carbonate-CO2 fractionation, thus requiring an alternative process during or prior to carbonate formation. This paper explores two processes capable of contributing to the isotopic enrichments: 1) evaporative-driven Rayleigh distillation and 2) kinetic isotope effects related to cryogenic precipitation. In isolation, each process cannot reproduce the observed carbonate isotope values; however, a combination of these processes represents the most likely source for the extreme isotopic enrichments.
  
  
• Loftus, Luo, Fan, and Kite, Extreme weather variability on hot rocky exoplanet 55 Cancri e explained by magma temperature-cloud feedback, submitted. [ More] [arxiv]
  
  Observations of the ultra-short period rocky exoplanet 55 Cancri e (55 Cnc e) indicate that the planet's dayside infrared radiation fluctuates by a factor of at least six on sub-weekly timescales, for unknown reasons. We propose a feedback mechanism where increased reflective clouds cool surface magma, subsequently reducing cloud formation, which may offer a potential explanation for these phenomena. In this mechanism, under less cloudy conditions, stellar radiation heats the surface magma, causing it to release more silicate vapor, which then condenses to form reflective clouds. Once formed, these clouds reduce stellar insolation at the surface, leading to surface cooling, which in turn reduces vapor supply, decreasing cloudiness. A time lag between the temperature increase of surface magma and the subsequent increase in cloudiness (likely due to lagged atmospheric transport of cloud-forming vapor) enables self-sustained oscillations in surface temperature and cloud reflectivity. These oscillations manifest as variations in both the emitted thermal radiation and the reflected stellar radiation, causing variability in secondary eclipse depths across different wavelengths without significantly affecting the transit depth. Using a simple model, we find that diverse planetary parameters can reproduce the observations. Additionally, we demonstrate that secondary eclipse depths at different wavelengths can oscillate out of phase, consistent with recent observations by the James Webb Space Telescope. Finally, we discuss observational strategies to test this proposed mechanism on 55 Cancri e. If confirmed, observable ocean-atmosphere dynamics on exoplanets would open a new window into the composition, evolution, and fate of rocky planet volatiles.
  
  
• Kite, Gasda, Weitz, Thompson, Tutolo, Mondro, Farrand, Gupta, Schieber, Dietrich, Mangold, and Lewis, Hypotheses for the water and metal fluxes to the rippled Amapari Marker Band, Gale Crater, Mars, in review. [ More]
  
  This paper is in review.
  
  
• Xue, Bean, Zhang, Mahajan, Ih, Eastman, Lunine, Weiner Mansfield, Coy, Kempton, Koll, and Kite, JWST thermal emission of the terrestrial exoplanet GJ 1132 b, Astrophysical Journal Letters, 2024. [ More] [htm]
  
  We present thermal emission measurements of GJ 1132b spanning 5-12 μm obtained with the Mid-Infrared Instrument Low-Resolution Spectrometer on the James Webb Space Telescope. GJ 1132b is an M dwarf rocky planet with T_eq = 584 K and an orbital period of 1.6 days. We measure a white-light secondary eclipse depth of 140 ± 17 ppm, which corresponds to a dayside brightness temperature of Tp,dayside = 709 ± 31 K using improved star and planet parameters. This measured temperature is only 1σ below the maximum possible dayside temperature of a bare rock (i.e., assuming a zero-albedo planet with no heat redistribution, T_max = 746+14/-11 K). The emission spectrum is consistent with a featureless blackbody, which agrees with a wide range of possible surface compositions. By comparing forward models to the dayside emission spectrum, we rule out Earth-thickness (P approximately 1 bar) atmospheres with at least 1% H2O, atmospheres of any modeled thickness (10^-4 to 10² bars) that contain at least 1% CO2, and thick, Venus-like atmospheres (P greater than or similar to 100 bars) with at least 1 ppm CO₂ or H₂O. We therefore conclude that GJ 1132b likely does not have a significant atmosphere. This finding supports the concept of a universal "cosmic shoreline" given the high level of bolometric and extreme ultraviolet (EUV) and X-rays (collectively XUV) irradiation received by the planet.
  
  
• Weiner Mansfield, Xue, Zhang, Mahajan, Ih, Koll, Bean, Coy, Eastman, Kempton, Kite, and Lunine, No thick atmosphere on the terrestrial exoplanet Gl 486b, Astrophysical Journal Letters, in press, 2024. [ More] [arxiv]
  
  A primary science goal for JWST is to detect and characterize the atmospheres of terrestrial planets orbiting M dwarfs (M-Earths). The existence of atmospheres on M-Earths is highly uncertain because their host stars' extended history of high XUV irradiation may act to completely remove their atmospheres. We present two JWST secondary eclipse observations of the M-Earth Gl 486b (also known as GJ 486b) between 5-12 μm. We combined these observations with a precise analysis of the host star parameters to derive a planetary dayside temperature of Tp=865±14 K. We compared this temperature to the maximum expected temperature for a zero albedo, zero heat redistribution bare rock and derived a temperature ratio of R=(Tp,dayside)/(Tp,max)=0.97±0.01. This value is consistent with an airless body with a slight non-zero albedo or a thin atmosphere with <1% H2O or <1 ppm CO2. However, it is inconsistent with an Earth- or Venus-like atmosphere, and the spectrum shows no clear emission or absorption features. Additionally, our observations are inconsistent with the water-rich atmospheric scenario allowed by previous transit observations and suggest the transmission spectrum was instead shaped by stellar contamination (Moran et al. 2023). Given the potential for atmospheric escape throughout the system's greater than or equal to 6.6-Gyr lifetime (Diamond-Lowe et al. 2024), we conclude that the observations are likely best explained by an airless planet. This result is the most precise measurement yet of terrestrial exoplanet thermal emission with JWST, which places a strong constraint on the position of the "Cosmic Shoreline" between airless bodies and those with atmospheres.
  
  
• Warren, Wilson, Howard, Noblet, and Kite, Multiple exit breaches from young craters require surface melting and hundreds of meters of mid-latitude ice late in Mars history, Planetary Science Journal, 2024. [ More] [htm]
  
  Mars' tadpole craters are small, young craters whose crater rims are incised by one or more exit breaches but lack visible inlets. The tadpole forming climate records the poorly understood drying of Mars since the Early Hesperian. A third of tadpole craters have multiple breaches, therefore a process is needed that was able to generate crater rim incision in multiple locations. We use HiRISE data for four multiple breach tadpole craters to measure their crater fill, rims, and exit breaches. We compare these measurements and other data to our calculations of liquid water supply by rain, surface melting, groundwater discharge, and basal ice sheet melting to discriminate between four proposed formation hypotheses for tadpole breaches, favoring scenarios with ice-filled craters and supraglacial melting. We conclude that multiple breach tadpole craters record hundreds of meters of mid-latitude ice and climate conditions enabling intermittent melting in the Late Hesperian and Amazonian, suggesting that liquid water on Mars has been available in association with water ice for billions of years.
  
  
• Kite, Tutolo, Turner, Franz, Burtt, Bristow, Fischer, Milliken, Fraeman, and Zhou, Carbonate formation and fluctuating habitability on Mars, in review. [ More]
  
  This paper is in review.
  
  
• Tutolo, Hausrath, Kite, Rampe, Bristow, Downs, Peretyazhko, Thorpe, Grotzinger, Archer, Des Marais, Blake, Vaniman, Morrison, Chipera, Hazen, Morris, Tu, and 18 others, In situ evidence of an active ancient carbon cycle on ancient Mars, revised version resubmitted. [ More]
  
  This paper is in review.
  
  
• Kite, Basic limits on exoplanet biosignature false positives, in preparation. [ More]
  
  This paper is not yet published.
  
  
• Kite and Conway, Geological evidence for multiple climate transitions on Early Mars, Nature Geoscience, 2024. [ More] [htm] [gallery] [pdf]
  
  Recently it has become clear that Mars' climate supported rivers and lakes over a time span of >1 Gyr. On Earth, the past Gyr has seen global glaciations and hyperthermals. What similarly major climate transitions occurred on Early Mars, what caused them, and what are the implications for the likelihood of life on Mars? We review new findings about climate change on ancient Mars and hypotheses for climate-change triggers. On Mars, surface liquid water persisted intermittently into the second half of Mars' history . However, there is evidence for long dry spells, with some locations fully dry after the first billion years of Mars history. Possible triggers for these major habitability changes include volcanism, and changes in Mars' mean obliquity. Future missions to test hypotheses for the mechanism of the Early Mars greenhouse effect, and to determine if a deep aquifer persists today, would be important steps forward in understanding the habitability of planets in general.
  
  
• Gu, Peng, Ji, Zhang, Yang, Hoyos, Hirschmann, Kite, and Fischer, Composition of Earth's initial atmosphere and fate of accreted volatiles set by core formation, Earth and Planetary Science Letters, 2024. [ More] [htm] [pdf]
  
  See published paper.
  
  
• Rapin, Dromart, Clark, Schieber, Kite, Kah, Thomson, Meslin, Gasnault, Gasda, and Lanza, Sustained Wet-Dry Cycling on Early Mars, Nature, 2023. [ More] [htm]
  
  The presence of perennially wet surface environments on early Mars is well documented, but little is known about short-term episodicity in the early hydroclimate. Post-depositional processes driven by such short-term fluctuations may produce distinct structures, yet these are rarely preserved in the sedimentary record. Incomplete geological constraints have led global models of the early Mars water cycle and climate to produce diverging results. Here we report observations by the Curiosity rover at Gale Crater indicating that high-frequency wet-dry cycling occurred in early Martian surface environments. We observe exhumed centimetric polygonal ridges with sulfate enrichments, joined at Y-junctions, that record cracks formed in fresh mud owing to repeated wet-dry cycles of regular intensity. Instead of sporadic hydrological activity induced by impacts or volcanoes, our findings point to a sustained, cyclic, possibly seasonal, climate on early Mars. Furthermore, as wet-dry cycling can promote prebiotic polymerization, the Gale evaporitic basin may have been particularly conducive to these processes. The observed polygonal patterns are physically and temporally associated with the transition from smectite clays to sulfate-bearing strata, a globally distributed mineral transition. This indicates that the Noachian-Hesperian transition (3.8-3.6 billion years ago) may have sustained an Earth-like climate regime and surface environments favourable to prebiotic evolution.
  
  
• Peterson, Benneke, Collins, Piaulet, Crossfield, Ali-Dib, Christiansen, Gagne, Faherty, Kite, and 58 others, A Temperate Earth-sized Planet With Tidal Heating Transiting an M6 Star, Nature, 2023. [ More] [htm]
  
  Temperate Earth-sized exoplanets around late-M dwarfs offer a rare opportunity to explore under which conditions planets can develop hospitable climate conditions. The small stellar radius amplifies the atmospheric transit signature, making even compact secondary atmospheres dominated by N2 or CO2 amenable to characterization with existing instrumentation. Yet, despite large planet search efforts, detection of low-temperature Earth-sized planets around late-M dwarfs has remained rare and the TRAPPIST-1 system, a resonance chain of rocky planets with seemingly identical compositions, has not yet shown any evidence of volatiles in the system. Here we report the discovery of a temperate Earth-sized planet orbiting the cool M6 dwarf LP 791-18. The newly discovered planet, LP 791-18d, has a radius of 1.03 +/- 0.04 REarth and an equilibrium temperature of 300-400K, with the permanent night side plausibly allowing for water condensation. LP 791-18d is part of a coplanar system4 and provides a so-far unique opportunity to investigate a temperate exo-Earth in a system with a sub-Neptune that retained its gas or volatile envelope. On the basis of observations of transit timing variations, we find a mass of 7.1 +/- 0.7 MEarth for the sub-Neptune LP 791-18c and a mass of 0.9+/-0.5 MEarth for the exo-Earth LP 791-18d. The gravitational interaction with the sub-Neptune prevents the complete circularization of LP 791-18d's orbit, resulting in continued tidal heating of LP 791-18d's interior and probably strong volcanic activity at the surface.
  
  
• Fan, Jansen, Mischna, and Kite, Why are mountaintops cold? The transition of surface lapse rate on dry planets, Geophysical Research Letters, 2023. [ More] [htm]
  
  The wet-to-dry transition of Mars is recorded by a changing distribution of rivers, which was interpreted as the result of a decorrelation between surface temperature and elevation with a thinner atmosphere. Here we use a climate model to re-examine the interpretation. We find that the weakening of the greenhouse effect, rather than atmospheric pressure, accounts for the decorrelation. The decorrelation happens near surface pressure ~0.1 bar for a pure CO₂ atmosphere, or longwave optical depth ~1 for a gray gas. Under the weak greenhouse limit, the surface is mainly heated by insolation and thus surface temperature decorrelates with elevation. Under the strong greenhouse limit, the surface is mainly heated by the atmosphere, whose temperature is controlled by advection and convection over the lowlands. Our results suggest that the correlation between river distribution and elevation should be re-examined with different greenhouse forcings and a low atmospheric pressure.
  
  
• Meyer, Milliken, Stack, Edgar, Rampe, Turner, Lewis, Kite, Caravaca, Vasavada, Dietrich, Bryk, Gasnault, Le Mouélic, Seeger, and Sheppard, Geological Context and Significance of the Clay-Sulfate Transition Region in Mount Sharp, Gale Crater, Mars: An Integrated Assessment Based on Orbiter and Rover Data, in press. [ More] [paper]
  
  On Mars, phyllosilicate ("clay") minerals are often associated with older terrains, and sulfate minerals are associated with younger terrains, and this dichotomy is taken as evidence that Mars' surface dried up over time. Therefore, in situ investigation of the Mount Sharp strata in Gale crater, which record a shift from dominantly clay-bearing to sulfate-bearing minerals, as seen in visible-near-infrared orbital reflectance spectra, is a key science objective for the Mars Science Laboratory (MSL) Curiosity rover mission. Here, we present regional (orbiter-based) and in situ (rover-based) evidence for a low-angle erosional unconformity that separates the lacustrine and marginal lacustrine deposits of the Carolyn Shoemaker formation from the dominantly eolian deposits of the lower Mirador formation within the orbitally defined clay-sulfate transition region. The up-section record of wetter (Carolyn Shoemaker formation) to drier (lower Mirador formation) depositional conditions is accompanied by distinct changes in diagenesis. Clay minerals occur preferentially within the Carolyn Shoemaker formation and are absent within the lower members of the Mirador formation. At and above the proposed unconformity, strata are characterized by an increase in diagenetic nodules enriched in X-ray amorphous Mg-sulfate. Early clay formation in the Carolyn Shoemaker formation may have created a hydraulic barrier such that later migrating magnesium- and sulfur-rich fluids accumulated preferentially within the lower members of the Mirador formation. The proposed unconformity may have also acted as a fluid conduit to further promote Mg-sulfate nodule formation at the Carolyn Shoemaker-Mirador formation boundary. These results confirm an association of the clay-sulfate transition with the drying of depositional environments, but they also suggest that at least some orbital sulfate signatures within the region are not time-congruent with the environmental signals extracted from primary sedimentology. Our findings highlight that complex interactions among primary depositional environment, erosion, and diagenesis contribute to the transition in clay-sulfate orbital signatures observed in the stratigraphy of Mount Sharp.
  
  
• Warren and Kite, Narrow range of early habitable Venus scenarios permitted by modelling of oxygen loss and radiogenic argon degassing, Proceedings of the National Academy of Sciences, 2023. [ More] [htm] [SI] [pdf]
  
  Whether Venus was ever habitable is a key question driving missions to Earth's sister planet in the next decade. Venus today has a dry, O2-poor atmosphere, but recent work has proposed that early Venus may have had liquid water and reflective clouds that could have sustained habitable conditions until 0.7 Ga. Water present at the end of a habitable era must since have been lost by photodissociation and H escape, causing buildup of atmospheric oxygen. We present a time-dependent model of Venus's atmospheric composition starting from the end of a hypothetical habitable era with surface liquid water. We find that O2 loss to space, oxidation of reduced atmospheric species, oxidation of lava, and oxidation of a surface magma layer formed in a runaway greenhouse climate can remove O2 from up to 500 m global equivalent layer (GEL) (30% of an Earth ocean), unless melts on Venus had a much lower oxygen fugacity than Mid Ocean Ridge melts on Earth, which increases the upper limit twofold. Volcanism is required to supply oxidizable fresh basalt and reduced gases to the atmosphere but also contributes 40Ar. Consistency with Venus's modern atmospheric composition occurs in less than 0.4% of runs, in a narrow parameter range where the reducing power introduced by O2 loss processes can balance O2 introduced by H escape. Our models favor hypothetical habitable eras ending before 3 Ga and very reduced melt oxygen fugacities three log units below the fayalite-magnetite-quartz buffer (fO2 less than FMQ-3), among other constraints.
  
  
• Hu, Gaillard, and Kite, Narrow loophole for H2-dominated atmospheres on habitable rocky planets around M dwarfs, Astrophysical Journal Letters, 2023. [ More] [htm] [pdf]
  
  Habitable rocky planets around M dwarfs that have H2-dominated atmospheres, if they exist, would permit characterizing habitable exoplanets with detailed spectroscopy using JWST, owing to their extended atmospheres and small stars. However, the H2-dominated atmospheres that are consistent with habitable conditions cannot be too massive, and a moderate-size H2-dominated atmosphere will lose mass to irradiation-driven atmospheric escape on rocky planets around M dwarfs. We evaluate volcanic outgassing and serpentinization as two potential ways to supply H2 and form a steady-state H2-dominated atmosphere. For rocky planets of 1-7 Earth mass and early, mid, and late M dwarfs, the expected volcanic outgassing rates from a reduced mantle fall short of the escape rates by >~1 order of magnitude, and a generous upper limit of the serpentinization rate is still less than the escape rate by a factor of a few. Special mechanisms that may sustain the steady-state H2-dominated atmosphere include direct interaction between liquid water and mantle, heat-pipe volcanism from a reduced mantle, and hydrodynamic escape slowed down by efficient upper-atmospheric cooling. It is thus unlikely to find moderate-size, H2-dominated atmospheres on rocky planets of M dwarfs that would support habitable environments.
  
  
• Zaki, Edgett, Pajola, Kite, Davis, Mangold, Madof, Lucchetti, Grindrod, Hughes, Sangwan, Thomas, Schuster, Gupta, Cremonese, and Castelltort, Prolonged record of hydroclimatic changes at Antoniadi Crater, Mars, Journal of Geophysical Research - Planets, 2023. [ More] [htm]
  
  The first billion years of Martian geologic history consisted of surface environments and landscapes dramatically different from those seen today, with flowing liquid water sculpting river channels and ponding to form bodies of water. However, the hydro-climatic context, the frequency, and the duration under which these systems existed remain uncertain. Addressing these fundamental questions may improve our understanding of early Mars's climate. Here, we reconstruct a long-lived archive consisting of an array of fluvial systems inside Antoniadi crater - (9.58 x 10^4 km^2) - one of the largest lake basins on Mars. We found that fluvial activity occurred throughout four major intermittent active intervals during the Late Noachian to Early Amazonian (~3.7 to >2.4 Ga). This resulted in at least two major lakes, which formed during periods of markedly increased surface runoff production. The record of these four riverine phases is preserved in fluvial ridges, valley networks, back-stepping or down-stepping fan-shaped landforms, and terrace-like formations within an outlet canyon. These morphologies point to lake-controlled base-level fluctuations suggestive of episodic precipitation-fed surface runoff punctuated by intermittent catastrophic floods that were capable of breaching crater-lake rims and incising outlet canyons. Fluvial-deposit thickness, junction angles of channels, and lake morphometry suggest that riverine systems lasted at least 10^3 - 10^6 years and occurred episodically under primarily arid and semi-arid climates. These findings place new regional constraints on the fluvial frequency, longevity, and climatic regime of one of the largest martian lakes, thereby bolstering the hypothesis that episodic warming likely punctuated the planet's early history.
  
  
• Barclay, and others including Kite, The transmission spectrum of the potentially rocky planet L 98-59 c, in review. [ More]
  
  We present observations of the 1.35+/-0.07 Earth-radius planet L 98-59 c using Wide Field Camera~3 on the Hubble Space Telescope. L 98-59 is a nearby (10.6 pc), bright (H=7.4 mag), M3V star that harbors three small, transiting planets. As one of the closest known transiting multi-planet systems, L 98-59 offers one of the best opportunities to probe and compare the atmospheres of rocky planets that formed in the same stellar environment. We measured the transmission spectrum of L 98-59 c during a single transit, with the extracted spectrum showing marginal evidence for wavelength-dependent transit depth variations which would indicate the presence of an atmosphere. Forward modeling was used to constrain possible atmospheric compositions of the planet based on the shape of the transmission spectrum. Although L 98-59 is a fairly quiet star, we have seen evidence for stellar activity, and therefore we cannot rule out a scenario where the source of the signal originates with inhomogeneities on the host-star surface. While intriguing, our results are inconclusive and additional data is needed to verify any atmospheric signal. Fortunately, additional data will soon be collected from both HST and JWST. Should this result be confirmed with additional data, L 98-59 c would be the first planet smaller than 2 Earth-radii with a detected atmosphere, and among the first small planets with a known atmosphere to be studied in detail by the JWST.
  
  
• Coy and Kite, Diskworld: modeling the limited sensitivity of long-term planetary habitability to tectonic noise, in revision. [ More]
  
  This paper is in review.
  
  
• Brinkman, Weiss, Dai, Huber, Kite, et al., TOI-561 b: A low density ultra-short period "rocky" planet around a metal-poor star, Astronomical Journal, 2023. [ More] [arxiv]
  
  TOI-561 is a galactic thick disk star hosting an ultra-short period (0.45 day orbit) planet with a radius of 1.37 REarth, making it one of the most metal-poor ([Fe/H] = -0.41) and oldest (~10 Gyr) sites where an Earth-sized planet has been found. We present new simultaneous radial velocity measurements (RVs) from Gemini-N/MAROON-X and Keck/HIRES, which we combined with literature RVs to derive a mass of Mb=2.24+/-0.20 MEarth. We also used two new Sectors of TESS photometry to improve the radius determination, finding Rb=1.37+/-0.04 REarth, and confirming that TOI-561 b is one of the lowest-density super-Earths measured to date (rho(b)= 4.8+/-0.5 g/cm3). This density is consistent with an iron-poor rocky composition reflective of the host star's iron and rock-building element abundances; however, it is also consistent with a low-density planet with a volatile envelope. The equilibrium temperature of the planet (~2300 K) suggests that this envelope would likely be composed of high mean molecular weight species, such as water vapor, carbon dioxide, or silicate vapor, and is likely not primordial. We also demonstrate that the composition determination is sensitive to the choice of stellar parameters, and that further measurements are needed to determine if TOI-561 b is a bare rocky planet, a rocky planet with an optically thin atmosphere, or a rare example of a non-primordial envelope on a planet with a radius smaller than 1.5 REarth.
  
  
• Jansen, Kang, Kite, and Zeng, Energetic constraints on ocean circulations of icy ocean worlds, The Planetary Science Journal, 2023. [ More] [htm] [pdf]
  
  Globally ice-covered oceans have been found on multiple moons in the solar system and may also have been a feature of Earth's past. However, relatively little is understood about the dynamics of these ice-covered oceans, which affect not only the physical environment but also any potential life and its detectability. A number of studies have simulated the circulation of icy-world oceans, but have come to seemingly widely different conclusions. To better understand and narrow down these diverging results, we discuss the energetic constraints for the circulation on ice-covered oceans, focusing in particular on Snowball Earth, Europa, and Enceladus. The energy input that can drive ocean circulation on ice-covered bodies can be associated with heat and salt fluxes at the boundaries as well as ocean tides and librations. We show that heating from the solid core balanced by heat loss through the ice sheet can drive an ocean circulation, but the resulting flows would be relatively weak and strongly affected by rotation. Salt fluxes associated with freezing and melting at the ice sheet boundary are unlikely to energetically drive a circulation, although they can shape the large-scale circulation when combined with turbulent mixing. Ocean tides and librations may provide an energy source for such turbulence, but the magnitude of this energy source remains highly uncertain for the icy moons, which poses a major obstacle to predicting the ocean dynamics of icy worlds and remains an important topic for future research.
  
  
• Kite and Noblet, High and dry: billion-year trends in the aridity of river-forming climates on Mars, Geophysical Research Letters, 2022. [ More] [arxiv] [htm] [pdf] [SI]
  
  Mars' wet-to-dry transition is a major environmental catastrophe, yet the spatial pattern, tempo, and cause of drying are poorly constrained. We built a globally-distributed database of constraints on Mars late-stage paleolake size relative to catchment area (aridity index), and found evidence for climate zonation as Mars was drying out. Aridity increased over time in southern midlatitude highlands, where lakes became proportionally as small as in modern Nevada. Meanwhile, intermittently wetter climates persisted in equatorial and northern-midlatitude lowlands. This is consistent with a change in Mars' greenhouse effect that left highlands too cold for liquid water except during a brief melt season, or alternatively with a fall in Mars' groundwater table. The data are consistent with a switch of unknown cause in the dependence of aridity index on elevation, from high-and-wet early on, to high-and-dry later. These results sharpen our view of Mars' climate as surface conditions became increasingly stressing for life.
  
  
• Whittaker, Malik, Ih, Kempton, Mansfield, Bean, Kite, Koll, Kronin, and Hu, The detectability of rocky planet surface and atmosphere composition with JWST: the case of LHS 3844 b, Astronomical Journal, 2022. [ More] [arxiv] [htm] [pdf]
  
  The spectroscopic characterization of terrestrial exoplanets over a wide spectral range from the near- to the mid-infrared will be made possible for the first time with the JWST. One challenge is that it is not known a priori whether such planets possess optically thick atmospheres or even any atmospheres altogether. However, this challenge also presents an opportunity, the potential to detect the surface of an extrasolar world. This study explores the feasibility of characterizing with the JWST the atmosphere and surface of LHS 3844b, the highest signal-to-noise rocky thermal emission target among planets that are cool enough to have nonmolten surfaces. We model the planetary emission, including the spectral signal of both the atmosphere and surface, and we explore all scenarios that are consistent with the existing Spitzer 4.5 micron measurement of LHS 3844b from Kreidberg et al. In summary, we find a range of plausible surfaces and atmospheres that are within 3 sigma of the observationless reflective metal-rich, iron-oxidized, and basaltic compositions are allowed, and atmospheres are restricted to a maximum thickness of 1 bar, if near-infrared absorbers at greater than or similar to 100 ppm are included. We further make predictions on the observability of surfaces and atmospheres and find that a small number (approx. 3) of eclipse observations should suffice to differentiate between surface and atmospheric features. We also perform a Bayesian retrieval analysis on simulated JWST data and find that the surface signal may make it harder to precisely constrain the abundance of atmospheric species and may falsely induce a weak H2O detection.
  
  
• Li, Kite, and Keating, The age and erosion rate of young sedimentary rock on Mars, The Planetary Science Journal, 2022. [ More] [arxiv] [htm] [pdf]
  
  The Medusae Fossae Formation (MFF) is an enigmatic sedimentary unit near Mars' equator with an uncertain formation process and age. Due to the heavily wind-eroded surface, it is difficult to determine the age of the MFF using a one-parameter model based on the crater size-frequency distribution function using existing crater count data (Tanaka 2000; Kerber & Head 2010). We create a new two parameter model that estimates both age and a constant erosion rate by treating cratering as a random Poisson process. Our study uses new crater count data collected from Context Camera (CTX) imagery for both the MFF and other young equatorial sedimentary rock. Based on our new model, the Central MFF formed >1.5 Ga and had low erosion rates (<650 nm/a), whereas East MFF, Far East MFF, and Zephyria Planum most likely formed <1.5 Ga and had higher erosion rates (>740 nm/a). The top of Aeolis Mons (informally known as Mount Sharp) in Gale Crater and Eastern Candor have relatively young ages and low erosion rates. Based on estimated erosion rates (since fast erosion permits metastable shallow ice), we also identify several sites including Zephyria Planum as plausible locations of shallow subsurface equatorial water ice that is detectable by Gamma Ray Spectroscopy (GRS) or Neutron Spectroscopy (NS). In addition to confirming <1.5 Ga sedimentary rock formations on Mars and distinguishing older and younger MFF sites, we find that fast-eroding locations have younger ages and MFF locations with slower erosion have older best-fit ages.
  
  
• Damiano, and others including Kite, A transmission spectrum of the sub-Earth planet L98-59 b in 1.1-1.7 micron, Astronomical Journal, 2022. [ More] [arxiv] [htm] [pdf]
  
  With the increasing number of planets discovered by the Transit Exoplanet Survey Satellite, the atmospheric characterization of small exoplanets is accelerating. L98-59 is an M-dwarf hosting a multiplanet system, and so far, four small planets have been confirmed. The innermost planet b is ~15% smaller and ~60% lighter than Earth, and should thus have a predominantly rocky composition. The Hubble Space Telescope observed five primary transits of L98-59 b in 1.1-1.7 micron, and here we report the data analysis and the resulting transmission spectrum of the planet. We measure the transit depths for each of the five transits and, by combination, we obtain a transmission spectrum with an overall precision of ~20 ppm in for each of the 18 spectrophotometric channels. With this level of precision, the transmission spectrum does not show significant modulation, and is thus consistent with a planet without any atmosphere or a planet having an atmosphere and high-altitude clouds or haze. The scenarios involving an aerosol-free, H2-dominated atmosphere with H2O or CH4 are inconsistent with the data. The transmission spectrum also disfavors, but does not rule out, an H2O-dominated atmosphere without clouds. A spectral retrieval process suggests that an H2-dominated atmosphere with HCN and clouds or haze may be the preferred solution, but this indication is nonconclusive. Future James Webb Space Telescope observations may find out the nature of the planet among the remaining viable scenarios.
  
  
• Kite, Mischna, Fan, Morgan, Wilson, and Richardson, Changing spatial distribution of water flow charts major change in Mars' greenhouse effect, Science Advances, 2022. [ More] [htm] ["Research Highlight" in Nature Astronomy]
  
  Early Mars had rivers and lakes, but it remains unclear whether the river-forming climates were warm and wet, or cold and icy. Past climate on Mars can be probed using the spatial distribution of climate-sensitive landforms. We analyzed global databases of water-worked landforms for changes in the spatial distribution of rivers over time. We found a decline over time in the preferred elevation for water-worked landforms, corresponding to a shift from >3.6 Ga elevation control to <3.6 Ga latitudinal banding. These changes are simply explained, by comparison to a simplified meltwater model driven by an ensemble of global climate models, as the result of greater than or similar to 10 K global cooling, from global average surface temperature T >= 268 K to T ~ 258 K, due to a weaker greenhouse effect. In other words, Early Mars wet climates were warm first, and colder later. Analysis of the greenhouse effect within our global climate model ensemble indicates that this shift was primarily driven by waning non-CO2 radiative forcing, rather than changes in CO2 radiative forcing. This suggests alternatives to the hypothesis that the decline of surface habitability on Mars was associated with atmospheric decay. Non-CO2 radiative forcing continued intermittently through ~3 Ga, and the spatial distribution of paleo-rivers on Mars is equally consistent with a thick paleo-atmosphere and with a thin paleo-atmosphere. Recognition of shifts in the pattern of water flow over time opens the door to simultaneously constraining both the climate in each era and also the drivers of long term climate change on Mars.
  
  
• Kite, Kreidberg, Schaefer, Caracas, and Hirschmann, "Earth cousins" are new targets for planetary materials research, EoS, 2021. [ More] [htm] [pdf]
  
  Among exoplanets, true Earth twins are hard to characterize, but there are other worlds, "Earth cousins" - a little bigger or a little hotter - that we can still use to understand planetary habitability. More lab and numerical experiments are needed to make the most of this opportunity.
  
  
• Hu, Damiano, Scheucher, Kite, Seager, and Rauer, Unveiling shrouded oceans on temperate sub-Neptunes via transit signatures of solubility equilibria vs. gas thermochemistry, Astrophysical Journal Letters, 2021. [ More] [arxiv] [htm] [pdf]
  
  The recent discovery and initial characterization of sub-Neptune-sized exoplanets that receive stellar irradiance of approximately Earth's raised the prospect of finding habitable planets in the coming decade, because some of these temperate planets may support liquid water oceans if they do not have massive H2/He envelopes and are thus not too hot at the bottom of the envelopes. For planets larger than Earth, and especially planets in the 1.7-3.5 R_Earth population, the mass of the H2/He envelope is typically not sufficiently constrained to assess the potential habitability. Here we show that the solubility equilibria vs. thermochemistry of carbon and nitrogen gases results in observable discriminators between small H2 atmospheres vs. massive ones, because the condition to form a liquid-water ocean and that to achieve the thermochemical equilibrium are mutually exclusive. The dominant carbon and nitrogen gases are typically CH4 and NH3 due to thermochemical recycling in a massive atmosphere of a temperate planet, and those in a small atmosphere overlying a liquid-water ocean are most likely CO2 and N2, followed by CO and CH4 produced photochemically. NH3 is depleted in the small atmosphere by dissolution into the liquid-water ocean. These gases lead to distinctive features in the planet's transmission spectrum, and a moderate number of repeated transit observations with the James Webb Space Telescope should tell apart a small atmosphere vs. a massive one on planets like K2-18 b. This method thus provides a way to use near-term facilities to constrain the atmospheric mass and habitability of temperate sub-Neptune exoplanets.
  
  
• Kite, Steele, Mischna, and Richardson, Warm early Mars surface enabled by high-altitude water ice clouds, Proceedings of the National Academy of Sciences, 2021. [ More] [htm] [pdf] [From The Cover] [Sky & Telescope]
  
  Despite receiving just 30% of the Earth's present-day insolation, Mars had water lakes early in the planet's history, due to an unknown warming mechanism. A possible explanation for the >10² yr-long lake-forming climates (Haberle et al. 2017, Kite 2019) is warming by water ice clouds (Segura et al. 2008, Urata & Toon 2013). However, this cloud greenhouse has proved difficult to replicate, and has been argued to require unrealistically high-altitude optically thick clouds (Wordsworth 2016, Ramirez & Kasting 2017). Here, we use a global climate model (GCM) to show that a cloud greenhouse can warm a Mars-like planet to global average annual-mean temperature (T) ~ 265 K, which is warm enough for low-latitude lakes, and stay warm for centuries or longer, but only if the planet has spatially patchy surface water sources. Warm, stable climates involve surface ice (and low clouds) only at locations much colder than the average surface temperature. At locations horizontally distant from these surface cold traps, clouds are found only at high altitudes, which maximizes warming. Radiatively significant clouds persist because ice particles resublimate as they fall, moistening the subcloud layer so that modest updrafts can sustain clouds. The resulting climates are arid (area-averaged surface relative humidity ~ 25%). In a warm, arid climate, lakes could be fed by groundwater upwelling, or by melting of ice following a cold-to-warm transition. Our results are consistent with the warm and arid climate favored by interpretation of geologic data (Grotzinger et al. 2014, Ramirez & Craddock 2018), and support the cloud greenhouse hypothesis.
  
  
• Stucky de Quay, Goudge, Kite, Fassett, and Guzewich, Limits on runoff episode duration for early Mars: integrating lake hydrology and climate models, Geophysical Research Letters, 2021. [ More] [htm] [pdf] [SI]
  
  Fluvio-lacustrine features on the martian surface attest to a climate that was radically different in the past. Since climate models have difficulty sustaining a liquid hydrosphere at the surface, multiple cycles of runoff episodes may have characterized the ancient Mars climate. A fundamental question thus remains: what was the duration of these runoff-producing episodes? Here we use morphometric measurements from newly identified coupled lake systems (containing both an open- and a closed-basin lake). We combined hydrological balances with precipitation outputs from climate models, and found that breaching runoff episodes likely lasted 10² - 10⁵ yr; other episodes may have been shorter but could not be longer. Runoff episode durations are model-dependent and spatially variable, and no climate model scenario can satisfy a unique duration for all coupled systems. In the near future, these quantitative constraints on early Mars lake persistence may be tested through in situ observations from Perseverance rover.
  
  
• Holo, Kite, Wilson, and Morgan, The timing of alluvial fan formation on Mars, The Planetary Science Journal, 2021. [ More] [htm] [pdf] [code]
  
  The history of rivers on Mars is an important constraint on Martian climate evolution. The timing of relatively young, alluvial fan-forming rivers is especially important, at Mars' Amazonian atmosphere is thought to have been too thin to consistently support surface liquid water. Previous regional studies suggsted that alluvial fans formed primarily between the Early Hesperian and the Early Amazonian. In this study, we describe how a combination of a global impact crater database, a global geologic map, a global alluvial fan database, and statistical models can be used to estimate the timing of alluvial fan formation across Mars. Using our global approach and improved statistical modeling, we find that alluvial fan formation likely persisted into the last ~2.5 Gyr, well into the Amazonian period. However, the data we analyzed was insufficient to place constraints on the duration of alluvial fan formation. Going forward, more crater data will enable tighter constraints on the parameters estimated in our models and thus further inform our understanding of Mars' climate evolution.
  
  
• Kite and Schaefer, Water on hot rocky exoplanets, Astrophysical Journal Letters, 2021. [ More] [htm] [pdf] [code]
  
  Data suggest that most super-Earths formed as gas-rich sub-Neptunes, but whether super-Earths still have atmospheres is unknown. We identify a pathway by which sub-Neptunes can develop long-lived 10-2000 bar H2O-dominated atmospheres during their conversion to Super-Earths, and show that this is a common outcome for efficient interaction between a nebula-derived atmosphere and oxidized magma, followed by atmospheric loss. H2O that is made by reduction of iron oxides in the magma is highly soluble in the magma, forming a dissolved reservoir that is protected from loss so long as the H2-dominated atmosphere persists, and whose large size buffers the H2O atmosphere against loss after the H2 has dispersed. This idea is imminently testable with JWST and has numerous implications for the interpretation of radial velocity data for transiting super-Earths.
  
  
• Ermakov, Park, Roa, Castillo-Rogez, Keane, Nimmo, Kite, Sotin, Lazio, Steinbrügge, Howell, Bills, Hemingway, Viswanathan, Tobie, and Lainey, A recipe for the geophysical exploration of Enceladus, The Planetary Science Journal, 2021. [ More] [htm] [pdf]
  
  Orbital geophysical investigations of Enceladus are critical to understanding its energy balance. Mapping Enceladus' gavity field, improving the accuracy of the physical libration amplitude, and measuring Enceladus' tidal response would provide critical constraints on the internal structure, and establish a framework for assessing Enceladus' long-term habitability. This kind of investigation could be carried out as part of a life search mission at little additional cost.
  
  
• Z. Liu, Y. Liu, Pan, Zhao, Kite, Wu, and Zou, Inverted channel belts and floodplain clays to the East of Tempe Terra, Mars: implications for persistent fluvial activity on Early Mars, Earth and Planetary Science Letters, 2021. [ More] [htm] [pdf]
  
  The climate on early Mars is a major unsolved problem. It is unclear whether early Mars was warm and wet or cold and icy. Morphological features on Mars such as sinuous ridges could provide critical constraints to address this issue. Here we investigate several sinuous ridges to the east of Temp Terra, Mars, and find they may have recorded persistent fluvial activity on early Mars. Our analaysis indicates that these ridges may represent exhumation of the channel belts and overbank deposits formed from meandering rivers over significant geologic time. Layered smectite-bearing mienrals, distributed over the ridge flanks, could be detrital or authigenic floodplain clays. Our interpretation of the stratigraphic relationships indicates that the layered smectite-bearing materials lie between channel belt deposits, supporting the floodplain interpretation. Our results suggest that a persistent warming event has persisted for a geologically significant interval (>1500 yr) during the Noachian period of Mars.
  
  
• Warren, Holo, Kite, and Wilson, Overspilling small craters on a dry Mars: Insights from breach erosion modeling, Earth and Planetary Science Letters, 2021. [ More] [htm] [pdf]
  
  Understanding when, where, and how frequently liquid water was stable on Mars since the Late Noachian/Early Hesperian (3.2-3.9 Ga) is important for understanding the evolution of Mars' climate and hydrology. Some relatively young features on Mars require multiple wetting events to form, whereas others are consistent with single wetting events. Small and rare exit breach craters or "pollywogs" are craters between 0.5 and 15 km in diameter with valleys leading away from the lowest point on their rims but no visible inlet valleys. These craters must have been filled with water to the point of overspill to form the observed valleys. The two possible water sources are precipitation and ground water. In this paper we use measurements from Digital Elevation Models (DEMs) of 18 pollywog craters (21 outlet valleys) and a 0-D breach erosion model to determine whether pollywog exit breach valleys are consistent with a single crater overspill event, or if their formation requires multiple overspill events. Our model predicts runaway erosion for two pollywog exit breaches. No runaway erosion is observed. We discuss potential explanations for this mismatch between the data and our model. We also show that the majority of pollywog craters on Mars are consistent with formation during a single crater overspill event. However, no existing climate models for Hesperian Mars (including impact- induced climates) are capable of providing the precipitation rates or snowmelt rates required to fill a pollywog crater and erode the observed outlet valley in a single event. Three pollywog craters require either multiple events or sustained water supply to drive ero sion. We discuss potential source mechanisms for crater-fillling water.
  
  
• Fan, Tan, Shaw, Kite, Reducing surface wetness leads to tropical hydrological cycle regime transition, Geophysical Research Letters, 2021. [ More] [htm] [pdf]
  
  Earth's modern climate is characterized by wet, rainy deep tropics, however, paleoclimate and planetary science have revealed a wide range of hydrological cycle regimes connected to different external parameters. Here we investigate how surface wetness affects the tropical hydrological cycle. When surface wetness is decreased in an Earth-like general circulation model, the tropics remain wet but the transition from a rainy to a rain-free regime. The rain-free regime occurs when surface precipitation is suppressed as negative evaporation (surface condensation) balances moisture flux convergence. The regime transition is dominated by near-surface relative humidity changes in contrast to the hypothesis that relative humidity changes are small. We show near-surface relative humidity changes responsible for the regime transition are controlled by re-evaporation of stratiform precipitation near the lifting condensation level. Re-evaporation impacts the near-surface through vertical mixing. Our results reveal a new rain-free tropical hydrological cycle regime that goes beyond the wet/dry paradigm.
  
  
• Kite and Barnett, Exoplanet secondary atmosphere loss and revival, Proceedings of the National Academy of Sciences, 2020. [ More] [arxiv] [htm] [pdf] [SI] [code] ["Research Highlight" in Nature Astronomy]
  
  The next step on the path toward another Earth is to find atmospheres similar to those of Earth and Venus - high-molecular-weight (secondary) atmospheres - on rocky exoplanets. Many rocky exoplanets are born with thick (> 10 kbar) H₂-dominated atmospheres but subsequently lose their H₂; this process has no known Solar System analog. We study the consequences of early loss of a thick H₂ atmosphere for subsequent occurrence of a high-molecular-weight atmosphere using a simple model of atmosphere evolution (including atmosphere loss to space, magma ocean crystallization, and volcanic outgassing). We also calculate atmosphere survival for rocky worlds that start with no H₂. Our results imply that most rocky exoplanets orbiting closer to their star than the Habitable Zone that were formed with thick H₂-dominated atmospheres lack high-molecular-weight atmospheres today. During early magma ocean crystallization, high-molecular-weight species usually do not form long-lived high-molecular-weight atmospheres; instead they are lost to space alongside H₂. This early volatile depletion also makes it more difficult for later volcanic outgassing to revive the atmosphere. However, atmospheres should persist on worlds that start with abundant volatiles (waterworlds). Our results imply that in order to find high-molecular-weight atmospheres on warm exoplanets orbiting M-stars, we should target worlds that formed H₂-poor, that have anomalously large radii, or which orbit less active stars.
  
  
• Heard and Kite, A probabilistic case for a large missing carbon sink on Mars after 3.5 billion years ago, Earth and Planetary Science Letters, 2020. [ More] [htm] [pdf]
  
  Mars has a thin (6 mbar) CO2 atmosphere currently. There is strong evidence for paleolakes and rivers formed by warm climates on Mars, including after 3.5 billion years (Ga) ago, which indicates that a CO2 atmosphere thick enough to permit a warm climate was present at these times. Since Mars no longer has a thick CO2 atmosphere, it must have been lost. One possibility is that Martian CO2 was lost to space. Oxygen escape rates from Mars are high enough to account for loss of a thick CO2 atmosphere, if CO2 was the main source of escaping O. But here, using H isotope ratios, O escape calculations, and quantification of the surface O sinks on Mars, we show for the first time that O escape from Mars after 3.5 Ga must have been predominantly associated with the loss of H2O, not CO2, and therefore it is unlikely that >=250 mbar Martian CO2 has been lost to space in the last 3.5 Ga, because such results require highly unfavored O loss scenarios. It is possible that the presence of young rivers and lakes on Mars could be reconciled with limited CO2 loss to space if crater chronologies on Mars are sufficiently incorrect that all apparently young rivers and lakes are actually older than 3.5 Ga, or if climate solutions exist for sustained runoff on Mars with atmospheric CO2 pressure <250 mbar. However, our preferred solution to reconcile the presence of <3.5 Gya rivers and lakes on Mars with the limited potential for CO2 loss to space is a large, as yet undiscovered, geological C sink on Mars.
  
  
• Kite, Fegley, Schaefer, and Ford, Atmosphere origins for exoplanet sub-Neptunes, Astrophysical Journal, 2020. [ More] [htm] [pdf]
  
  Planets with 2 R_{Earth} < R < 3 R_{Earth} and orbital period < 100 d are abundant; these sub-Neptune exoplanets are not well understood. For example, Kepler sub-Neptunes are likely to have deep magma oceans in contact with their atmospheres, but little is known about the effect of the magma on the atmosphere. Here we study this effect using a basic model, assuming that volatiles equilibrate with magma at T ~ 3000 K. For our Fe-Mg-Si-O-H model system, we find that chemical reactions between the magma and the atmosphere and dissolution of volatiles into the magma are both important. Thus, magma matters. For H, most moles go into the magma, so the mass target for both H2 accretion and H2 loss models is weightier than is usually assumed. The known span of magma oxidation states can produce sub-Neptunes that have identical radius but with total volatile masses varying by 20-fold. Thus, planet radius is a proxy for atmospheric composition but not for total volatile content. This redox diversity degeneracy can be broken by measurements of atmosphere mean molecular weight. We emphasise H2 supply by nebula gas, but also consider solid-derived H2O. We find that adding H2O to Fe probably cannot make enough H2 to explain sub-Neptune radii because >10^3-km thick outgassed atmospheres have high mean molecular weight. The hypothesis of magma-atmosphere equilibration links observables such as atmosphere H2O/H2 ratio to magma FeO content and planet formation processes. Our model's accuracy is limited by the lack of experiments (lab and/or numerical) that are specific to sub-Neptunes; we advocate for such experiments.
  
  
• Holo and Kite, The spatial signature of a changing ancient impactor population for Mars, Icarus, 2020. [ More] [htm] [pdf]
  
  Using (i) a global database of Mars impact craters and (ii) angular two-point correlation statistics to quantify local to regional crater clustering, we found that degraded craters on low-lying middle-Noachian-highland terrains were subject to spatially-patchy crater obliteration by surface processes, while older, higher-standing craters on the early Noachian highlands remain consistent with being drawn from a spatially uniform distribution. This result supports the hypothesis that the multi-sloped Noachian CSFD results from an early impactor population that changed during the Noachian, rather than from extensive obliteration of craters < 32 km in diameter by surface processes such as fluvial erosion, volcanic flooding, and aeolian infilling. The cause of the change in impactor populations remains unknown.
  
  
• Archer, Kite, and Lusk, The ultimate cost of carbon, Climatic Change, 2020. [ More] [paper]
  
  We estimate the potential ultimate social cost of fossil-fuel carbon to all future human generations throughout the 200-kyr duration of the climate impacts from fossil carbon combustion. Costs are integrated through time assuming continued human reliance on our biological habitat, and that each generation of humanity values its world as much as we do. The impact of climate on near-future GDP from economic models, combined with long-term temperature estimates from climate and geochemical cycle models, integrates to an eventual cost of about $20,000 per ton of CO2, up to $100,000 per ton if future human population and economic activity eventually scales with Earth's agricultural production capacity. Eventual sea level rise of order 50 meters has the potential to reduce the extent of human habitat by about 10%, for an interval of time that will be determined by soil formation and isostatic rebound response time scales, of order 10 kyr. Assuming economic activity ultimately scales with habitat, the ultimate cost of sea level rise could be of order $5,000 per ton. These costs together are three orders of magnitude higher than the present-day value of the social cost of carbon ($20-50 per ton), and almost two orders more costly than the cost of atmospheric removal of CO2 ($600 per ton for direct air capture).
  
  
• Kite, Fegley, Schaefer, and Ford, Superabundance of exoplanet sub-Neptunes explained by fugacity crisis, Astrophysical Journal Letters, 2019. [ More] [arxiv] [pdf] [code] [Physics Today]
  
  Transiting planets with radii 2-3 Earth radius are much more numerous than larger planets. We propose that this drop-off is so abrupt because at approximately 3 Earth radius, base-of-atmosphere pressure is high enough for the atmosphere to readily dissolve into magma, and this sequestration acts as a strong brake on further growth. The viability of this idea is demonstrated using a simple model. Our results support extensive magma-atmosphere equilibration on sub-Neptunes, with numerous implications for sub-Neptune formation and atmospheric chemistry.
  
  
• Warren, Kite, Williams, and Horgan, Through the thick and thin: New constraints on Martian paleopressure history 3.8-4 Ga from small exhumed craters, JGR-Planets, 2019. [ More] [htm] [pdf]
  
  Mars' climate history depends in part on its atmospheric pressure evolution, but most existing constraints on atmospheric pressure are indirect. Thin atmospheres allow small objects to reach the surface and form impact craters, therefore ancient impact craters can constrain past atmospheric pressure. To identify ancient craters preserved in sedimentary rocks and exhumed by wind erosion we use HiRISE orthoimages, anaglyphs, and digital terrain models (DTMs). We compare measured crater populations from two sites to predictions from an atmosphere-impactor interaction model for atmospheres of different pressures. Our upper limits on continuous atmospheric pressure are 1.9±0.1 bar around 4 Ga and 1.5±0.1 bar at 3.8±0.2 Ga. We demonstrate that atmospheric pressure cannot have been continuously above these upper limits. During the interval 3.8±0.2 Ga, our crater counts require that atmospheric pressure was less than 5% of Earth's modern pressure for at least 10^4 yrs, or at higher pressure for a correspondingly longer duration of time (at least 10^5-10^6 yrs at 1.5 bar for our Mawrth phyllosilicates and Meridiani Planum data respectively). Therefore, atmospheric pressure around 4 Ga was either continuously 1.9±0.1 bar, or varied between higher (>1.9 bar) and lower (<1.9 bar) pressures. Similarly, atmospheric pressure at 3.8±0.2 Ga was either continuously 1.5±0.1 bar, or varied between higher (>1.5 bar) and lower (<1.5 bar) pressures. Finally, we synthesize all available paleopressure estimates for early Mars to constrain a 2-component model of Mars' long-term atmospheric pressure evolution. In our model, atmospheric pressures <1 bar early in Mars' history best fit existing paleopressure constraints.
  
  
• Stucky de Quay, Kite, and Mayer, Prolonged fluvial activity from channel-fan systems on Mars, JGR-Planets, 2019. [ More] [htm] [pdf]
  
  Alluvial fans on Mars, which are primarily sourced from erosional alcoves incised into crater rims, record a period of increased surface runoff which ended >1 Ga. However, we lack quantitative constraints on the frequency and duration of river-forming processes and the climatic conditions which accompanied these long-term habitable episodes. Here we use bedrock erosion and sediment transport models to show that cumulative time span of wet activity was between 100 yr - 1 Myr. We use Context Camera (CTX) digital elevation models to compile a dataset of >200 channels upstream of depositional fans and determine key fluvial geometry metrics. Results from calculating Mars stream power parameters are compared to great escarpment channels on Earth and globally distributed terrestrial bedrock rivers. Although Martian channel profile morphologies fall within the range of those on Earth, they are slightly less concave-up and steeper for a given drainage area. Timescales depend strongly on poorly constrained variables such as erodibility and grain size. Channel morphologies, intermittencies, spatial distributions, and orientations collectively suggest an arid climate and a source from snowmelt on steep crater rims, possibly from obliquity-paced insolation variations or orographic accumulation. Derived timescales are consistent with erosion rates and intermittencies observed on Earth and do not support short-lived or catastrophic sources, instead attesting to long-lived, recurring wet activity.
  
  
• Kite, Mayer, Wilson, Davis, Lucas, and Stucky de Quay, Persistence of intense, climate-driven runoff late in Mars history, Science Advances, 2019. [ More] [htm] [pdf] [SI] [data] [CNN] [National Geographic] [USA Today]
  
  Mars dry today, but numerous precipitation-fed paleo-rivers are found across the planet's surface. These rivers' existence is a challenge to models of planetary climate evolution. We report results from a global survey indicating that for a given catchment area, rivers on Mars were wider than rivers on Earth today. This difference is not the result of Mars' lower surface gravity. We use the scale (width and wavelength) of Mars paleo-rivers as a proxy for past runoff production. Using multiple methods, we infer that intense >(3-20) kg/m²/day runoff production persisted until <3 Ga and probably <1 Ga, and was globally distributed. Therefore, the intense runoff production inferred from the results of the Mars Science Laboratory rover was not a short-lived or local anomaly. Rather, precipitation-fed runoff production was globally distributed, intense, and persisted intermittently over a time span of >1 Gyr. Our improved history of Mars river runoff places new constraints on the unknown mechanism that caused wet climates on Mars.
  
  
• de Kleer, Nimmo, and Kite, Variability in Io's volcanism on timescales of periodic orbital changes, Geophysical Research Letters, 2019. [ More] [htm] [pdf] [New York Times]
  
  The widespread volcanism on the jovian moon Io is powered by tidal heating, yet we lack a deep understanding of how this distinctive heating process affects the locations, timing, or intensities of Io's eruptions. We show that the quasiperiodic behavior of the volcano Loki Patera in 1987-2018 matches the timescales for the evolution of Io's eccentricity and semimajor axis (~480 and ~460 days). If this orbital forcing is driving Loki Patera's variability, a low-pass geophysical filter such as poroelastic flow, or a resonant amplification of Io's wobble, could account for the importance of these long-period orbital variations despite their small amplitudes. The peak volcanic response is predicted to roughly coincide with Io's maximum eccentricity, consistent with the observations. High cadence observations over the next several years have the potential to conclusively discriminate between orbital versus geophysical control of Loki Patera's variability.
  
  
• Kite, Geologic constraints on Early Mars climate, Space Science Reviews, 2019. [ More] [htm] [pdf]
  
  Early Mars climate research has well-defined goals (Mars Exploration Program Analysis Group 2018). Achieving these goals requires geologists and climate modelers to coordinate. Coordination is easier if results are expressed in terms of well-defined parameters. Key parameters include the following quantitative geologic constraints. (1) Post-3.4 Ga precipitation-sourced water runoff in some places exceeded > 1 km column. (2) There is no single Early Mars climate problem: the traces of ≥ 2 river-forming periods are seen. Relative to rivers that formed earlier in Mars history, rivers that formed later in Mars history are found preferentially at lower elevations, and show a stronger dependence on latitude. (3) The duration of the longest individual river-forming climate was >(10² - 10³) yr, based on paleolake hydrology. (4) Peak runoff production was >0.1 mm/hr. However, (5) peak runoff production was intermittent, sustained (in a given catchment) for only <10% of the duration of river-forming climates. (6) The cumulative number of wet years during the valley-network-forming period was >10⁵ yr. (7) Post-Noachian light-toned, layered sedimentary rocks took >10⁷ yr to accumulate. However, (8) an "average" place on Mars saw water for <10⁷ yr after the Noachian, suggesting that the river-forming climates were interspersed with long globally-dry intervals. (9) Geologic proxies for Early Mars atmospheric pressure indicate pressure was not less than 0.012 bar but not much more than 1 bar. A truth table of these geologic constraints versus currently published climate models shows that the late persistence of river-forming climates, combined with the long duration of individual lake-forming climates, is a challenge for most models.
  
  
• Kite and Melwani Daswani, Geochemistry constrains global hydrology on Early Mars, Earth and Planetary Science Letters, 2019. [ More] [htm] [SI] [pdf]
  
  Ancient hydrology is recorded by sedimentary rocks on Mars. The most voluminous sedimentary rocks that formed during Mars' Hesperian period are sulfate-rich rocks, explored by the Opportunity rover from 2004-2012 and soon to be investigated by the Curiosity rover at Gale crater. A leading hypothesis for the origin of these sulfates is that the cations were derived from evaporation of deep-sourced groundwater, as part of a global circulation of groundwater. Global groundwater circulation would imply sustained warm Earthlike conditions on Early Mars. Global circulation of groundwater including infiltration of water initially in equilibrium with Mars' CO2 atmosphere implies subsurface formation of carbonate. We find that the CO2 sequestration implied by the global groundwater hypothesis for the origin of sulfate-rich rocks on Mars is 30-5000 bars if the Opportunity data are representative of Hesperian sulfate-rich rocks, which is so large that (even accounting for volcanic outgassing) it would bury the atmosphere. This disfavors the hypothesis that the cations for Mars' Hesperian sulfates were derived from upwelling of deep sourced groundwater. If, instead, Hesperian sulfate-rich rocks are approximated as pure Mg-sulfate (no Fe), then the CO2 sequestration is 0.3-400 bars. The low end of this range is consistent with the hypothesis that the cations for Mars' Hesperian sulfates were derived from upwelling of deep sourced groundwater. In both cases, carbon sequestration by global groundwater circulation actively works to terminate surface habitability, rather than being a passive marker of warm Earthlike conditions. Curiosity will soon be in a position to discriminate between these two hypotheses. Our work links Mars sulfate cation composition, carbon isotopes, and climate change.
  
  
• Mansfield, Kite, Hu, Koll, Malik, Bean, and Kempton, Identifying atmospheres on rocky exoplanets through inferred high albedo, Astrophysical Journal, 2019. [ More] [arxiv] [pdf]
  
  The upcoming launch of the James Webb Space Telescope (JWST) means that we will soon have the capability to characterize the atmospheres of rocky exoplanets. However, it is still unknown whether such planets orbiting close to M dwarf stars can retain their atmospheres, or whether high-energy irradiation from the star will strip the gaseous envelopes from these objects. We present a new method to detect a rocky exoplanet atmosphere, by using thermal emission during secondary eclipse to infer a high dayside albedo that could only be explained by bright clouds. Based on calculations for plausible surface conditions, we calculate that a high albedo could be unambiguously interpreted as a signal of an atmosphere for planets with substellar temperatures of T_ss = (420-1250) K. This range corresponds to equilibrium temperatures of T_eq = (300-880) K. We compare the inferred albedos of eight possible planet surface compositions to cloud albedo calculations. We determine that a layer of small-particle (<0.1 μm radius) clouds with optical depth greater than τ= 0.1 - 0.9, or larger-particle clouds with optical depths greater than τ = 3-6, would have high enough albedos to be distinguishable from a bare rock surface. This method of detecting an atmosphere on a rocky planet is complementary to existing methods for detecting atmospheres, because it provides a way to detect atmospheres with pressures below 1 bar (e.g. Mars), which are too tenuous to transport significant heat but thick enough to host high-albedo clouds.
  
  
• Koll, Malik, Mansfield, Kempton, Kite, Abbot, and Bean, Identifying candidate atmospheres on rocky M dwarf planets via eclipse photometry, Astronomical Journal, 2019. [ More] [arxiv]
  
  Most rocky planets in the galaxy orbit a cool host star, but there is large uncertainty among theoretical models whether these planets are able to retain an atmosphere. The James Webb Space Telescope (JWST) might be able to settle this question empirically, but most proposals for doing so are based on spectroscopy and require large observational effort. Here we show that infrared photometry of secondary eclipses could quickly identify 'candidate' atmospheres, by searching for rocky planets with atmospheres thick enough that atmospheric heat transport noticeably reduces their dayside thermal emission compared to that of a bare rock. Assuming a nearby rocky planet amenable to atmospheric characterization, we find that JWST should be able to confidently detect the heat redistribution signal of an O(1) bar atmosphere with a single eclipse. A single eclipse is generally much less than the effort needed to infer an atmosphere on the same planet via transmission or emission spectroscopy. Candidate atmospheres can be further validated via follow-up spectroscopy or phase curves. However, even without further validation, infrared photometry with JWST could enable a first atmospheric survey of rocky exoplanets that are too hot to be habitable. Knowing whether hot, rocky planets around M dwarfs have atmospheres is important not only for understanding the evolution of uninhabitable worlds: if atmospheres are common on hot planets, then cooler, potentially habitable planets around M dwarfs are also likely to have atmospheres.
  
  
• Malik, Kempton, Koll, Mansfield, Bean, and Kite, Analyzing Atmospheric Temperature Profiles and Spectra of M-Dwarf Rocky Planets, Astrophysical Journal, 2019. [ More] [arxiv]
  
  The highly anticipated launch of the James Webb Space Telescope (JWST) will open up the possibility of comprehensively measuring the thermal emission spectra of rocky exoplanets orbiting M dwarfs to detect and characterize their atmospheres. In preparation for this opportunity, we present model atmospheres for three terrestrial M-dwarf planets particularly amenable to secondary eclipse spectroscopy --- TRAPPIST-1b, GJ 1132b, and LHS 3844b. Using three limiting cases of candidate atmospheric compositions (pure H₂O, pure CO₂ and solar abundances) we calculate temperature-pressure profiles and emission and reflection spectra in radiative-convective equilibrium, including the effects of a solid surface at the base of the atmosphere. Our results differ appreciably from simpler parameterized models of super-Earth atmospheres in terms of the overall temperatures and the temperature gradient, which has important observational consequences. We find that the atmospheric radiative transfer is significantly influenced by the cool M-star irradiation; H₂O and CO₂ absorption bands in the near-infrared are strong enough to absorb a sizeable fraction of the incoming stellar light at low pressures, which leads to temperature inversions in the upper atmosphere. The non-gray band structure of gaseous opacities in the infrared is hereby an important factor. Opacity windows are muted at higher atmospheric temperatures, so we expect temperature inversions to be common only for sufficiently cool planets. We also find that pure CO₂ atmospheres exhibit lower overall temperatures and stronger reflection spectra compared to models of the other two compositions. We estimate that for GJ 1132b and LHS 3844b we should be able to distinguish between different atmospheric compositions with JWST. The emission lines from the predicted temperature inversions are currently hard to measure, but high resolution spectroscopy with future Extremely Large Telescopes may be able to detect them.
  
  
• Kite and Ford, Habitability of exoplanet waterworlds, Astrophysical Journal, 2018. [ More] [htm] [pdf] [Scientific American]
  
  Many habitable zone exoplanets are expected to form with water mass fractions higher than that of the Earth. For rocky exoplanets with 10-1000x Earth's H₂O but without H₂, we model the multi-Gyr evolution of ocean temperature and chemistry, taking into account C partitioning, high-pressure ice phases, and atmosphere-lithosphere exchange. Within our model, for Sun-like stars, we find that: (1) the duration of habitable surface water is strongly affected by ocean chemistry; (2) possible ocean pH spans a wide range; (3) surprisingly, many waterworlds retain habitable surface water for >1 Gyr, and (contrary to previous claims) this longevity does not necessarily involve geochemical cycling. The key to this cycle-independent planetary habitability is that C exchange between the convecting mantle and the water ocean is curtailed by seafloor pressure on waterworlds, so the planet is stuck with the ocean mass and ocean cations that it acquires during the first 1% of its history. In our model, the sum of positive charges leached from the planetary crust by early water-rock interactions - coincidentally - often within an order of magnitude of the early-acquired atmosphere+ocean inorganic C inventory overlaps. As a result, pCO₂ is frequently in the "sweet spot" (0.2-20 bar) for which the range of semimajor axis that permits surface liquid water is about as wide as can be. Because the width of the HZ in semimajor axis defines (for Sun-like stars) the maximum possible time span of surface habitability, this effect allows for Gyr of habitability as the star brightens. We illustrate our findings by using the output of an ensemble of N-body simulations as input to our waterworld evolution code. Thus (for the first time in an end-to-end calculation) we show that chance variation of initial conditions, with no need for geochemical cycling, can yield multi-Gyr surface habitability on waterworlds.
  
  
• Holo, Kite, and Robbins, Mars obliquity history constrained by elliptic crater orientations, Earth and Planetary Science Letters, 2018. [ More] [htm] [pdf] [code] [news coverage in Science]
  
  The dynamics of Mars' obliquity are chaotic, and thus the historical ~3.5 Gyr obliquity probability density function (pdf) is highly uncertain and cannot be inferred from direct simulation alone. Obliquity is also a strong control on post-Noachian Martian climate, enhancing the potential for equatorial ice/snow melting and runoff at high obliquities (>40°) and enhancing the potential for wicking groundwater to the surface at low obliquities (<25°). We used the orientations of elliptical craters to constrain the true late-Hesperian onward obliquity pdf. To do so, we developed a forward model of the effect of obliquity on elliptic crater orientations using ensembles of simulated Martian impactors and ~ 3.5 Gyr-long Mars obliquity simulations. Comparison with a verified global database of elliptic crater orientations allowed us to invert the model for the best fit obliquity pdf. While several obliquity pdf's are consistent with the data, we computed weighted estimates for the mean late-Hesperian onward obliquity and for the fraction of that time spent with obliquity > 40°. Mean obliquity was likely low ~30°, and obliquity was high < 30% of the time. We rejected at the p = 0.025 level that mean obliquity was > 37° and that the obliquity was high > 41% of the time since the beginning of the late-Hesperian. We failed to reject low (~ 15°) mean obliquity solutions.
  
  
• Seybold, Kite, and Kirchner, Branching geometry of valley networks on Mars and Earth and its implications for early Martian climate, Science Advances, 2018. [ More] [pdf] [htm] ["Research Highlight" in Nature]
  
  Mars' surface bears the imprint of valley networks formed billions of years ago and their relicts can still be observed today. However, whether these networks were formed by groundwater sapping, ice melt, or fluvial runoff has been continuously debated. These different scenarios have profoundly different implications for Mars' climatic history, and thus for its habitability in the distant past. Recent studies on Earth revealed that channel networks in arid landscapes with more surface runoff branch at narrower angles, while in humid environments with more groundwater flow, branching angles are much wider. We find that valley networks on Mars generally tend to branch at narrow angles similar to those found in arid landscapes on Earth. This result supports the inference that Mars once had an active hydrologic cycle and that Mars' valley networks were formed primarily by overland flow erosion with groundwater seepage playing only a minor role.
  
  
• Mansfield, Kite, and Mischna, Effect of Mars atmospheric loss on snow melt potential in a 3.5-Gyr climate evolution model, JGR-Planets, 2018. [ More] [pdf]
  
  Post-Noachian Martian paleochannels and fluvial deposits suggest the presence of liquid water on the surface of Mars after about 3.5 Gya, but by this time conditions most favorable to melting no longer existed. We created a zero-dimensional surface energy balance model to explore what conditions could have led to surface liquid water. We combine the energy balance model with 3.5-Gyr physically consistent orbital histories to track melting conditions over the last 3.5 Gyr of Martian history. We find that melting is only allowed for high atmospheric pressures corresponding to exponential loss rates of dP/dt \propto (1/t)^-4.2 or faster, but that small amounts of melting are produced for a rate of atmospheric loss that is within one standard deviation of the rate calculated from initial measurements made by the Mars Atmosphere and Volatile EvolutioN (MAVEN) mission. For loss rates within two standard deviations of the initial MAVEN results, enough melting is produced to match geologic constraints on the formation of Hesperian river networks, assuming optimal surface properties such as albedo and thermal inertia, and assuming meting only occurs during the warmest part of the warmest season each Mars year. We also find that the rate of atmospheric loss has a larger effect on the surface energy balance than changes in Mars's mean obliquity.
  
  
• Steele, Kite, and Michaels, Crater mound formation by wind erosion on Mars, Journal of Geophysical Research - Planets, 2018. [ More] [htm] [pdf]
  
  Most of Mars' ancient sedimentary rocks by volume are in wind-eroded sedimentary mounds, but the connections between mound form and wind erosion are unclear. In particular, no numerical model has shown whether, or how, mounds can be formed. We perform mesoscale simulations of different crater and mound morphologies to understand the formation of sedimentary mounds. As crater depth increases, slope winds produce increased erosion near the base of the crater wall, forming mounds. Peak erosion rates occur when the crater depth is 2 km. Thus, for the first time, our results use a physically self-consistent model to show how a mound can emerge from initially flat infill. Mound evolution depends on the size of the host crater. In smaller craters mounds preferentially erode at the top, becoming more squat, while in larger craters mounds become steeper-sided. This agrees with observations where smaller craters tend to have proportionally shorter mounds, and larger craters have mounds encircled by moats. If a large-scale sedimentary layer blankets a crater, then as the layer recedes across the crater it will erode more towards the edges of the crater, resulting in a crescent-shaped moat. When a 160 km diameter mound-hosting crater is subject to a prevailing wind, the surface wind stress is stronger on the leeward side than on the windward side. This results in the mound 'marching upwind' over time, and forming a 'bat-wing' shape, as observed for Mt. Sharp in Gale crater.
  
  
• Gabasova and Kite, Compaction and sedimentary basin analysis on Mars, Planetary & Space Science, 2018. [ More] [pdf]
  
  Many of the sedimentary basins of Mars show patterns of faults and off-horizontal layers that, if correctly understood, could serve as a key to basin history. Sediment compaction is a possible cause of these patterns. We quantified the possible role of differential sediment compaction for two Martian sedimentary basins: the sediment fill of Gunjur crater (which shows concentric graben), and the sediment fill of Gale crater (which shows outward-dipping layers). We assume that basement topography for these craters is similar to the present-day topography of complex craters that lack sediment infill. For Gunjur, we find that differential compaction produces maximum strains consistent with the locations of observed graben. For Gale, we were able to approximately reproduce the observed layer orientations measured from orbiter image-based digital terrain models, but only with a >3 km-thick donut-shaped past overburden. It is not immediately obvious what geologic processes could produce this shape.
  
  
• Kite, Gaidos and Onstott, Valuing life detection missions, Astrobiology, 2018. [ More] [htm] [pdf]
  
  Recent discoveriesiply that Early Mars was habitable for life-as-we-know-it (Grotzinger et al. 2014); that Enceladus is habitable (Waite et al. 2017); and that many stars have Earth-sized exoplanets whose insolation favors surface liquid water (Dresig & Charbonneau 2013, Gaidos 2013). These exciting discoveries make it more likely that spacecraft now under construction - Mars 2020, ExoMars rover, JWST, Europa Clipper - could find habitable, or formerly habitable, environments. Did these environments see life? Given finite resources ($10bn/decade for the US ), how could we best test the hypothesis of a second tree of life? Here, we first state the case for and against flying life detection missions soon. Next, we assume that life detection missions will happen soon, and propose a framework for comparing the value of different life detection missions:
  
  Scientific value = (Reach x grasp x certainty x payoff) / $
  
  After discussing each term in this framework, we conclude that scientific value is maximized if life detection missions are set up as hypothesis tests. With hypothesis tesig, even a nondetection outcome is scientifically valuable.
  
  
• Spencer, Nimmo, Ingersoll, Hurford, Kite, Rhoden, Schmidt, and Howett, Plume Origins and Plumbing (Ocean to Surface), in Schenk et al. (eds.) Enceladus and the Icy Moons of Saturn, Univ. Ariz. Press, 2018. [ More] [pdf]
  
  The plume of Enceladus provides a unique window into subsurface processes the ice shell and ocean of an icy world. Thanks to a decade of observations and modeling, a coherence picture is emerging of a thin ice shell extending across the south polar region, cut through by fractures directly connected to the underlying ocean, and at least partially filled with water. The plume jets emerging from the fractures directly sample this water reservoir. The shell undergoes daily tidal flexing, which modulates plume activity by opening and closing the fractures. Dissipation in the ice and conduit water components due to this flexing is likely to generate the several Gigawatts of observed power, which is lost from the south pole as infrared radiation and plume latent heat.
  
  
• Kite, Gao, Goldblatt, Mischna, Yung, and Mayer, Methane bursts as a trigger for intermittent lake-forming climates on post-Noachian Mars, Nature Geoscience, 2017. [ More] [abstract] [pdf] [SI] [News & Views] ["Research Highlight" in Nature] [Los Angeles Times]
  
  Build-up of relatively young (<3.6 Ga) deltas and alluvial fans on Mars required lakes to persist for >3 Kyr (assuming dilute flow), and the watersheds' little-weathered soils indicate a climate history that was >99% dry. However, the lake-forming climates' trigger mechanism remains unknown. Here we show that these intermittency constraints, while inconsistent with many previously-proposed triggers for lake-forming climates, are consistent with a novel CH₄-burst mechanism. In this scenario, chaotic transitions in mean obliquity drive latitudinal shifts in temperature and ice loading that destabilize CH₄ clathrate. We shows that outgassed CH₄ builds up to levels whose radiative forcing is sufficient to modulate lake-forming climates for past clathrate hydrate stability zone occupancy fractions >0.04. Such occupancy fractions are consistent with CH₄ production by >3 Ga water-rock reactions. Individual lake-forming climate are curtailed to <10⁶ yr duration, consistent with data, by UV-limited CH₄ photolysis. Our results identify a new pathway for early Mars to undergo intermittent excursions to a warm, wet climate state.
  
  
• Melwani Daswani and Kite, Paleohydrology on Mars constrained by mass balance and mineralogy of pre-Amazonian sodium chloride lakes, JGR-Planets, 2017. [ More] [htm] [pdf]
  
  Chloride-bearing deposits on Mars record high-elevation lakes during the waning stages of Mars' wet era (mid-Noachian to late Hesperian). The water source pathways, seasonality, salinity, depth, lifetime, and paleoclimatic drivers of these widespread lakes are all unknown. Here we combine reaction-transport modeling, orbital spectroscopy, and new volume estimates from high-resolution digital terrain models, in order to constrain the hydrologic boundary conditions for forming the chlorides. Considering a T = 0 deg C system, we find: (1) individual lakes were >100 m deep and lasted decades or longer; (2) if volcanic degassing was the source of chlorine, then the water-to-rock ratio or the total water volume were probably low, consistent with brief excursions above the melting point and/or arid climate; (3) if the chlorine source was igneous chlorapatite, then Cl-leaching events would require a (cumulative) time of >10 yr at the melting point; (4) Cl masses, divided by catchment area, give column densities 0.1 - 50 kg Cl/m², and these column densities bracket the expected chlorapatite-Cl content for a seasonally-warm active layer. Deep groundwater was not required. Taken together, our results are consistent with Mars having a usually cold, horizontally segregated hydrosphere by the time chlorides formed.
  
  
• Kite, Sneed, Mayer, and Wilson, Persistent or repeated surface habitability on Mars during the Late Hesperian - Amazonian, Geophysical Research Letters, 2017. [ More] [htm] [pdf] [SI]
  
  Large alluvial fan deposits on Mars record the most recent undisputed habitable window of surface conditions (less than or similar to 3.5 Ga, Late Hesperian - Amazonian). We find net sedimentation rate <(4-8) microns/yr in the alluvial-fan deposits, using the frequency of craters that are interbedded with alluvial-fan deposits. Considering only the observed interbedded craters sets a lower bound of >20 Myr on the total time interval spanned by alluvial-fan aggradation, >10³-fold longer than previous lower limits. A more realistic approach that corrects for craters fully entombed in the fan deposits raises the lower bound to >(100-300) Myr. Several factors not included in our calculations would further increase the lower bound. The lower bound rules out fan-formation by a brief climate anomaly. Therefore, during the Late Hesperian - Amazonian on Mars, persistent or repeated processes permitted habitable surface conditions.
  
  
• Kite and Mayer, Mars sedimentary rock erosion rates constrained using crater counts, with applications to organic-matter preservation and to the global dust cycle, Icarus, 2017. [ More] [htm] [pdf] [SI]
  
  Small-crater counts on Mars light-toned sedimentary rock are often inconsistent with any isochron; these data are usually plotted then ignored. We show (using an 18-HiRISE-image, >10⁴ crater dataset) that these non-isochron crater counts are often well-fit by a model where crater production is balanced by crater obliteration via steady exhumation. For these regions, we fit erosion rates. We infer that Mars light-toned sedimentary rocks typically eroded at 10² nm/yr, when averaged over 10 km² scales and 10⁷-10⁸ yr timescales. Crater-based erosion-rate determination is consistent with independent techniques, but can be applied to nearly all light-toned sedimentary rocks on Mars. Erosion is sit enough that radiolysis cannot destroy complex organic matter at some locations (e.g. paleolake deposits at SW Melas), but radiolysis is a severe problem at other locations (e.g. Oxia Planum). The data suggest that the relief of the Valles Marineris mounds is currently being reduced by wind erosion, and that dust production on Mars <3 Gya greatly exceeds the modern reservoir of mobile dust.
  
  
• Kite, Sneed, Mayer, Lewis, Michaels, Hore, and Rafkin, Evolution of major sedimentary mounds on Mars, JGR-Planets, 2016. [ More] [data] [htm] [pdf]
  
  We present a new database of >300 layer-orientations from sedimentary mounds on Mars. These layer orientations, together with draped landslides, and draping of rocks over differentially-eroded paleo-domes, indicate that for the stratigraphically-uppermost ~1 km, the mounds formed by the accretion of draping strata in a mound-shape. The layer-orientation data further suggest that layers lower down in the stratigraphy also formed by the accretion of draping strata in a mound-shape. The data are consistent with terrain-influenced wind erosion, but inconsistent with tilting by flexure, differential compaction over basement, or viscoelastic rebound. We use a simple landscape evolution model to show how the erosion and deposition of mound strata can be modulated by obliquity. The model is driven by multi-Gyr calculations of Mars' chaotic obliquity and a parameterization of terrain-influenced wind erosion that is derived from mesoscale modeling. Our results suggest that mound-spanning unconformities with kilometers of relief emerge as the result of chaotic obliquity sits. Our results support the interpretation that Mars' rocks record intermittent liquid-water runoff during a >>100 Myr interval of sedimentary rock emplacement.
  
  
• Kite, Fegley, Schaefer, and Gaidos, Atmosphere-interior exchange on hot rocky exoplanets, Astrophysical Journal, 2016. [ More] [arxiv] [htm] [pdf]
  
  We provide estimates of atmospheric pressure and surface composition on short-period rocky exoplanets (with dayside magma pools and silicate vapor atmospheres). Atmospheric pressure tends toward vapor-pressure equilibrium with the surface composition, and surface composition is set by the balance between fractional vaporization and surface-interior exchange. We use basic models to show how surface-interior exchange is controlled by the planet's temperature, mass, and initial composition. We find:- (1) atmosphere-interior exchange is fast when the planet's bulk-silicate FeO concentration is low, and slow when FeO concentration is high; (2) magma pools are compositionally well-mixed for substellar temperatures less than or similar to 2400K, but compositionally variegated and rapidly variable for temperatures greater than or similar to 2400K; (3) currents within the magma pool tend to cool the top of the solid mantle (``tectonic refrigeration''); (4) contrary to earlier work, many magma planets have time-variable surface compositions.

• Kite and Rubin, Sustained eruptions on Enceladus explained by turbulent dissipation in tiger stripes, Proceedings of the National Academy of Sciences, 2016. [ More] [abstract] [pdf] [arxiv] [Physics Today] [*erratum*]
  
  Spacecraft observations suggest that the the geysers on Saturn's moon Enceladus draw water from a subsurface ocean, but the sustainability of conduits linking ocean and surface is not understood. The prevailing view is that the 100km-long fissures ("tiger stripes") sourcing the geysers are clamped shut by tidal stresses for much of Enceladus' 1.3 day orbit, and that liquid-water conduits should freeze over within weeks, so that eruptions should be intermittent. However, observations show sustained (though tidally modulated) geysering throughout each orbit, and since the 2005 discovery of the plumes. Peak geyser flux lags peak tidal extension by 1 radian, suggestive of resonance. Here we show that a simple model of the tiger stripes as tidally-flexed slots that puncture the ice shell can simultaneously explain the persistence of the eruptions through the tidal cycle, the phase lag, the maintenance of fissure eruptions over geological timescales, and the total power output of the tiger stripe terrain. The delay associated with flushing and refilling of O(1) m-wide slots with ocean water generates a phase lag relative to tidal forcing and helps to buttress slots against closure, while tidally pumped in-slot flow leads to heating and mechanical disruption that staves off slot freeze-out. Much narrower and much wider slots cannot be sustained. In the presence of long-lived slots, the 10⁶-yr average power output of the tiger stripe is buffered by a feedback between ice melt-back and subsidence to 5 GW, which is equal to the observed power output, suggesting long-term stability. Turbulent dissipation makes testable predictions for upcoming flybys by the Cassini spacecraft. Turbulent dissipation in long-lived slots helps maintain the ocean against freezing, maintains access by future Enceladus missions to ocean materials, and is plausibly the major energy source for tiger stripe activity.

• Richter, Chaussidon, Mendybaev, and Kite, Reassessing the cooling rate and geologic setting of Martian nakhlite meteorites with special emphasis on MIL 03346 and NWA 817, Geochimica et Cosmochimica Acta, 2016. [ More] [paper]
  
  Lithium concentration and isotopic fractionation profiles across augite grains from two Martian meteorites - MIL 03346 and NWA 817 - were used to determine their thermal history and implications for their geologic setting. The iron-magnesium zoning and associated magnesium isotopic fractionation of olivine grains from NWA 817 was also measured and provide a separate estimate of the cooling rate. The observed correlation of concentration with isotopic fractionation provides the essential evidence that the zoning of these grains was in fact due to diffusion and thus can be used as a measure of their cooling rate. The diffusion rate of lithium in augite depends on the oxygen fugacity, which has to be taken into account when determining a cooling rate based on the lithium zoning. The Fe-Mg exchange in olivine is much less sensitive to oxygen fugacity, but it is significantly anisotropic and for this reason we determined the direction relative to crystallographic axes of the line along which the Fe-Mg zoning was measured. We found that the cooling rate of NWA 817 determined from the lithium zoning in augite grains and that based on the Fe-Mg zoning of olivines are in good agreement at an oxygen fugacity close to that of quartz-fayalite-magnetite oxygen buffer, but not at the nickel- nickel oxide buffer that was previously assumed and resulted in what we now believe was a far too fast previous estimate of the cooling rate of NWA 817 based on the lithium zoning. The cooling rate of MIL 03346 was found to be resolvably faster than that of NWA 817 - of the order of 1 degrees/hr for the former and of the order of 0.1 degrees/hr for the latter. An important observation regarding the history of MIL 03346 and NWA 817 is that the lithium and Fe-Mg zoning are only observed where the augite or olivine is in contact with the mesostasis, which implies that they were already about 80% crystallized at the time diffusion began. The augite and olivine core compositions while very homogeneous are not in equilibrium with each other, which we interpret to imply that prior to the rapid cooling there must have been a protracted period of the order of years above the solidus, during which the much faster Fe-Mg exchange in olivine compared to that in augite allowed the olivine to maintain equilibrium with a changing melt composition while the augite was not significantly affected. We suggest two possible geological settings for the origin and evolution of MIL 03346 and NWA 817: (1) A slow cooling stage in a crystallization front in a crustal magma chamber, followed by eruption of melt plus portions of the crystallization front onto the surface where the final fast cooling took place at the bottom of a lava flow or melt pond, and (2) Eruption of a crystal laden melt as a thick long-lived lava flow where the crystals continued to grow as a cumulate and were rapidly cooled when the overlying lava layer was suddenly drained.

• Ehlmann, and others including Kite, The sustainability of habitability on terrestrial planets: insights, questions, and needed measurements from Mars for understanding the evolution of Earth-like worlds, JGR-Planets, 2016. [ More] [htm] [pdf]
  
  What allows a planet to be both within a potentially habitable zone and sustain habitability over long geologic time? With the advent of exoplanetary astronomy and the ongoing discovery of terrestrial-type planets around other stars, our own solar system becomes a key testing ground for ideas about what factors control planetary evolution. Mars provides the solar system's longest record of the interplay of the physical and chemical processes relevant to habitability on an accessible rocky planet with an atmosphere and hydrosphere. Here we review current understanding and update the timeline of key processes in early Mars history. We then draw on knowledge of exoplanets and the other solar system terrestrial planets to identify six broad questions of high importance to the development and sustaining of habitability (unprioritized): (1) Is small planetary size fatal? (2) How do magnetic fields influence atmospheric evolution? (3) To what extent does starting composition dictate subsequent evolution, including redox processes and the availability of water and organics? (4) Does early impact bombardment have a net deleterious or beneficial influence? (5) How do planetary climates respond to stellar evolution, e.g., sustaining early liquid water in spite of a faint young Sun? (6) How important are the timescales of climate forcing and their dynamical drivers? Finally, we suggest crucial types of Mars measurements (unprioritized) to address these questions: (1) in situ petrology at multiple units/sites; (2) continued quantification of volatile reservoirs and new isotopic measurements of H, C, N, O, S, Cl, and noble gases in rocks that sample multiple stratigraphic sections; (3) radiometric age dating of units in stratigraphic sections and from key volcanic and impact units; (4) higher-resolution measurements of heat flux, subsurface structure, and magnetic field anomalies coupled with absolute age dating. Understanding the evolution of early Mars will feed forward to understanding the factors driving the divergent evolutionary paths of the Earth, Venus, and thousands of small rocky extrasolar planets yet to be discovered.

• Borlina, Ehlmann, and Kite, Modeling the thermal and physical evolution of Mount Sharp's sedimentary rocks, Gale Crater, Mars, JGR-Planets, 2015. [ More] [htm] [pdf]
  
  Gale Crater, landing site of the Mars Science Laboratory (MSL), contains a central mound with 5 km of sedimentary stratigraphy (Aeolis Mons/Mt. Sharp). Understanding mound sedimentation, erosion, and diagenesis can constrain past geologic processes and the mound's organic preservation potential. Scenarios for mound fromation include: (1) complete filling of Gale followed by partial removal of sediments; (2) building of a central deposit with morphology controlled by slope winds and only incomplete sedimentary fill. Here we model sediment temperature-time paths for both scenarios, compare results with past MSL analyses, and provide scenario-dependent predictions of diagenesis along MSL's future traverse. Modeled erosion and deposition rates are 5-42 microns/yr, consistent with previously-published estimates. Evidence of diagenesis is expected, though spatial patterns and mineralogical predictions depend on Mars surface paleotemperature and sedimentation scenario. For (1), temperatures experienced by sediments should decrease monotonically over the traverse and up Mt. Sharp stratigraphy, whereas for (2) maximum temperatures are reached in the lower units of Mt. Sharp and thereafter decline or hold roughly constant. If early Mars surface temperatures were similar to modern Mars (mean: -50 degrees C), only select locations under select scenarios permit diagenetic fluids (T>0 degrees C). In contrast, if early Mars surface temperatures averaged 0 degrees C, diagenesis is predicted in most locations with maximum temperatures up to 150 degrees C. Comparing our predictions with future MSL results on diagenetic textures, secondary mineral assemblages, and the age and spatial variability of authigenic phases could constrain both mound formation processes and the physical context for liquid water on early Mars.

• Kite, Howard, Lucas, and Lewis, Resolving the era of river-forming climates on Mars using stratigraphic logs of river-deposit dimensions, Earth and Planetary Science Letters, 2015. [ More] [htm] [pdf] [SI]
  
  River deposits are one of the main lines of evidence that tell us that Mars once had a climate different from today, and so changes in river deposits with time tell us something about how Mars climate changed with time. In this study, we focus in on one sedimentary basin - Aeolis Dorsa - which contains an exceptionally high number of exceptionally well-preserved river deposits. We use changes in the river deposits' scale with stratigraphic elevation as a proxy for changes in river paleodischarge. Meander wavelengths tighten upwards and channel widths narrow upwards, and there is some evidence for a return to wide large-wavelength channels higher in the stratigraphy. Meander wavelength and channel width covary with stratigraphic elevation. The factor-of-1.5 to factor-of-2 variations in paleochannel dimensions with stratigraphic elevation correspond to ~2.6-fold variability in bank-forming discharge (using standard wavelength-discharge scalings and width-discharge scalings). Taken together with evidence from a marker bed for variability at ~10m stratigraphic distances, the variation in the scale of river deposits indicates that bank-forming discharge varied at both ~10m stratigraphic (10²-10⁶ yr) and ~100 m stratigraphic (10³ - 10⁹ yr) scales. Because these variations are correlated across the basin, they record a change in basin-scale forcing, rather than smaller-scale internal feedbacks. Changing sediment input leading to a change in characteristic slopes and/or drainage area could be responsible, and another possibility is changing climate (± 50 W/m² in peak energy available for snow/ice melt).

• Kite, Howard, Lucas, Armstrong, Aharonson, and Lamb, Stratigraphy of Aeolis Dorsa, Mars: stratigraphic context of the great river deposits, Icarus, 2015. [ More] [htm] [pdf] [SI]
  
  Unraveling the stratigraphic record is the key to understanding ancient climate change and past climate changes on Mars (Grotzinger et al. 2011). Stratigraphic records of river deposits hold particular promise because rain or snowmelt must exceed infiltration plus evaporation to allow sediment transport by rivers. Therefore, river deposits when placed in stratigraphic order could constrain the number, magnitudes, and durations of the wettest (and presumably most habitable) climates in Mars history. We use crosscutting relationships to establish the stratigraphic context of river and alluvial-fan deposits in the Aeolis Dorsa sedimentary basin, 10° E of Gale crater. At Aeolis Dorsa, wind erosion has exhumed a stratigraphic section of sedimentary rocks consisting of at least four unconformity-bounded rock packages, recording three or more distinct episodes of surface runoff. Early deposits (>700m thick) are embayed by river deposits (>400m thick), which are in turn unconformably draped by fan-shaped deposits (<100m thick) which we interpret as alluvial fans. Yardang-forming layered deposits (>900 m thick) unconformably drape all previous deposits.
  
  River deposits embay a dissected landscape formed of sedimentary rock. The river deposits are eroding out of at least two distinguishable units. There is evidence for pulses of erosion during the interval of river deposition. The total interval spanned by river deposits is >(1 x 10⁶ - 2 x 10⁷) yr, and this is extended if we include alluvial-fan deposits. Fan-shaped deposits unconformably postdate thrust faults which crosscut the river deposits. This relationships suggests a relatively dry interval of >4 x 10⁷ yr after the river deposits formed and before the fan-shaped deposits formed, based on probability arguments. Yardang-forming layered deposits unconformably postdate all of the earlier deposits. They contain rhythmite and their induration suggests a damp or wet (near-)surface environment. The time gap between the end of river deposition and the onset of yardang-forming layered deposits is constrained to >1 x 10⁸ yr by the high density of impact craters embedded at the unconformity. The time gap between the end of alluvial-fan deposition and the onset of yardang-forming layered deposits was at least long enough for wind-induced saltation abrasion to erode 20-30m into the alluvial-fan deposits. We correlate the yardang-forming layered deposits to the upper layers of Gale crater's mound (Mt. Sharp / Aeolis Mons), and the fan-shaped deposits to Peace Vallis fan in Gale crater. Alternations between periods of low mean obliquity and periods of high mean obliquity may have modulated erosion-deposition cycling in Aeolis. This is consistent with the results from an ensemble of simulations of Solar System evolution and the resulting history of the obliquity of Mars. Almost all of our simulations produce one or more intervals of continuously low mean Mars obliquity that are long enough to match our Aeolis Dorsa unconformity data.
  

• Kite, Williams, Lucas and Aharonson, Low palaeopressure of the martian atmosphere estimated from the size distribution of ancient craters, Nature Geoscience, 2014. [ More] [abstract] [pdf] [SI] [regional data] [local data] [News & Views] [Nature News] [Wired] [BBC News]
  
  The decay of the martian atmosphere - which is dominated by carbon dioxide - is a component of the long-term environmental change on Mars from a climate that once allowed rivers to flow to the cold and dry conditions of today. The minimum size of craters serves as a proxy for palaeopressure of planetary atmospheres, because thinner atmospheres permit smaller objects to reach the surface at high velocities and form craters. The Aeolis Dorsa region near Gale crater on Mars contains a high density of preserved ancient craters interbedded with river deposits and thus can provide constraints on atmospheric density at the time of fluvial activity. Here we use high-resolution images and digital terrain models from the Mars Reconnaissance Orbiter to identify ancient craters in deposits in Aeolis Dorsa that date to about 3.6 Gyr ago and compare their size distribution with models of atmospheric filtering of impactors. We obtain an upper limit of 0.9±0.1 bar for the martian atmospheric palaeopressure, rising to 1.9±0.2 bar if rimmed circular mesas - interpreted to be erosionally-resistant fills or floors of impact craters - are excluded. We assume target properties appropriate for desert alluvium: if sediment had rock-mass strength similar to bedrock at the time of impact, the paleopressure upper limit increases by a factor of up to two. If Mars did not have a stable multibar atmosphere at the time that the rivers were flowing - as suggested by our results - then a warm and wet CO₂/H₂O greenhouse is ruled out, and long-term average temperatures were most likely below freezing.
  

• Kite, Lewis, Lamb, Newman, and Richardson, Growth and form of the mound in Gale Crater, Mars: Slope-wind enhanced erosion and transport, Geology, 2013. [ More] [pdf] [SI] [code] [Red Planet Report] [news coverage in Science] [news coverage in Nature] [New York Times]
  

  Ancient sediments provide archives of climate and habitability on Mars. Gale Crater, the landing site for the Mars Science Laboratory (MSL), hosts a 5 km high sedimentary mound. Hypotheses for mound formation include evaporitic, lacustrine, fluviodeltaic, and aeolian processes, but the origin and original extent of Gale's mound is unknown. Here we show new measurements of sedimentary strata within the mound that indicate ~3° outward dips oriented radially away from the mound center, inconsistent with the first three hypotheses. Moreover, although mounds are widely considered to be erosional remnants of a once crater-filling unit, we find that the Gale mound's current form is close to its maximal extent. Instead we propose that the mound's structure, stratigraphy, and current shape can be explained by growth in place near the center of the crater mediated by wind-topography feedbacks. Our model shows how sediment can initially accrete near the crater center far from crater-wall katabatic winds, until the increasing relief of the resulting mound generates mound-flank slope-winds strong enough to erode the mound. Our results indicate mound formation by airfall-dominated deposition with a limited role for lacustrine and fluvial activity, and potentially limited organic carbon preservation. Morphodynamic feedbacks between wind and topography are widely applicable to a range of sedimentary mounds and ice mounds across the Martian surface, and possibly other planets.
  

• Kite, Halevy, Kahre, Wolff, and Manga, Seasonal melting and the formation of sedimentary rocks on Mars, Icarus, 2013. [ More] [pdf] [journal version] [astrobites] [Red Planet Report] [Planetary Society]
  

  A model for the formation and distribution of sedimentary rocks on Mars proposed. In this model (ISEE-Mars), the rate--limiting step is supply of liquid water from seasonal melting of snow or ice. The model is run for a 10² mbar pure CO₂ atmosphere, dusty snow, and solar luminosity reduced by 23%. For these conditions snow melts only near the equator, when obliquity and eccentricity are high, and when perihelion occurs near equinox. These requirements for melting are satisfied by 0.01-20% of the probability distribution of Mars' past spin-orbit parameters. This fraction is small, consistent with the geologic record of metastable surface liquid water acting as a "wet-pass filter" of Mars climate history, only recording orbital conditions that permitted surface liquid water. Total melt production is sufficient to account for observed aqueous alteration of the sedimentary rocks. The pattern of seasonal snowmelt is integrated over all spin-orbit parameters and compared to the observed distribution of sedimentary rocks. The global distribution of snowmelt has maxima in Valles Marineris, Meridiani Planum and Gale Crater. These correspond to maxima in the sedimentary-rock distribution. Higher pressures and especially higher temperatures lead to melting over a broader range of spin-orbit parameters. The pattern of sedimentary rocks on Mars most consistent with a model Mars paleoclimate that only rarely produced enough meltwater to precipitate aqueous cements (sulfates, carbonates, phyllosilicates and silica) and indurate sediment. This is consistent with observations suggesting that surface aqueous alteration on Mars was brief and at low water/rock ratio. The results suggest intermittency of snowmelt and long globally-dry intervals, unfavorable for past life on Mars. This model makes testable predictions for the Mars Science Laboratory Curiosity rover at Gale Crater's mound (Mount Sharp, Aeolis Mons). Gale Crater's mound is predicted to be a hemispheric maximum for snowmelt on Mars.
  

• Kite, Lucas, and Fassett, Pacing Early Mars river activity, Icarus, 2013. [ More] [pdf] [code] [supplementary table]
  

  The impactor flux early in Mars history was much higher than today, so sedimentary sequences include many buried craters. In combination with models for the impactor flux, observations of the number of buried craters can constrain sedimentation rates. Using the frequency of crater-river interactions, we find net sedimentation rate ≤ ~20-300 μm/yr at Aeolis Dorsa. This sets a lower bound of 1-15 Myr on the total interval spanned by fluvial activity around the Noachian-Hesperian transition. We predict that Gale Crater's mound (Aeolis Mons) took at least 10-100 Myr to accumulate, which is testable by the Mars Science Laboratory.

• Šrámek, McDonough, Kite, Lekić, Dye, and Zhong, Geophysical and geochemical constraints on geoneutrino fluxes from Earth's mantle, Earth and Planetary Science Letters, 2013. [ More] [pdf] [SI] ["Research Highlight" in Nature]
  
  Knowledge of the amount and distribution of radiogenic heating in the mantle is crucial for understanding the dynamics of the Earth, including its thermal evolution, the style and planform of mantle convection, and the energetics of the core. Although the flux of heat from the surface of the planet is robustly estimated, the contributions of radiogenic heating and secular cooling remain poorly defined. Constraining the amount of heat-producing elements in the Earth will provide clues to understanding nebula condensation and planetary formation processes early Solar System. Mantle radioactivity supplies power for mantle convection and plate tectonics, but estimates of mantle radiogenic heat production vary by a factor of more than 20. Recent experimental results demonstrate the potential for direct assessment of mantle radioactivity through observations of geoneutrinos, which are emitted by naturally occurring radionuclides. Predictions of the geoneutrino signal from the mantle exist for several established estimates of mantle composition. Here we present novel analyses, illustrating surface variations of the mantle geoneutrino signal for models of the deep mantle structure, including those based on seismic tomography. These variations have measurable differences for some models, allowing new and meaningful constraints on the dynamics of the planet. An ocean based geoneutrino detector deployed at several strategic locations will be able to discriminate between competing compositional models of the bulk silicate Earth.

• Kite and Howard, Commentary: Let's send the DoE to Alpha Centauri, Physics Today, September 2013. [pdf]

• Mangold, Kite, Kleinhans, Newsom, Ansan, Hauber, Kraal, Quantin-Nataf and Tanaka, The origin and timing of fluvial activity at Eberswalde Crater, Mars, Icarus, 2012. [ More] [pdf]
  

  The fan deposit in Eberswalde crater has been interpreted as strong evidence for sustained liquid water on early Mars with a paleolake formed during the Noachian period (>3.7 Gy). This location became a key region for understanding the Mars paleo-environment. Eberswalde crater is located 50 km north of the rim of the 150 km diameter crater Holden. Stratigraphic relationships and chronology obtained using recent Mars Express High Resolution Stereo Camera and Mars Reconnaissance Orbiter Context Camera images show that Eberswalde fluvial activity crosscuts Holden ejecta and thus postdates Holden crater, whose formation age is estimated from crater counts as Late Hesperian (3.5 Gy, depending on models). fluvial modeling shows that short term activity (over several years to hundreds of years) involving dense flows (with sediment:water ratio between 0.01 and 0.3) may be as good an explanation of the fluvial landforms as dilute flow over longer durations. Modeling of the thermal effect of the Holden impact in the Eberswalde watershed is used to evaluate its potential role in aqueous activity. The relative timing of the Holden impact and Eberswalde's fan is a constraint for future studies about the origin of these landforms. Holden ejecta form a weak and porous substrate, which may be easy to erode by fluvial incision. In a cold climate scenario, impact heating could have produced runoff by melting snow or ground ice. Any attempt to model fluvial activity at Eberswalde should take into account that it may have formed as late as the Late Hesperian, after the great majority of valley network formation and aqueous mineralization on Mars. This suggests that hypotheses for fan formation at Eberswalde by transient and/or localized processes (i.e. impact, volcanism, unusual orbital forcing) should be considered on a par with globally warmer climate.

• Rappaport, Levine, Chiang, El Mellah, Jenkins, Kalomeni, Kite, Kotson, Nelson, Rousseau-Nepton, and Tran, Possible disintegrating short-period Super-Mercury orbiting KIC 12557548, Astrophysical Journal, 2012. [ More] [pdf] [htm]
  

  We report on the discovery of stellar occultations, observed with Kepler, which recur periodically at 15.685 hr intervals, but which vary in depth from a maximum of 1.3% to a minimum that can be less than 0.2%. The star that is apparently being occulted is KIC 12557548, a V = 16 mag K dwarf with T_eff = 4400 K. The out-of-occultation behavior shows no evidence for ellipsoidal light variations, indicating that the mass of the orbiting object is less than ~3 MJ (for an orbital period of 15.7 hr). Because the eclipse depths are highly variable, they cannot be due solely to transits of a single planet with a fixed size. We discuss but dismiss a scenario involving a binary giant planet whose mutual orbit plane precesses, bringing one of the planetsto and out of a grazing transit. This scenario seems ruled out by the dynamical instability that would result from such a configuration. We also briefly consider an eclipsing binary, possibly containing an accretion disk, that either orbits KIC 12557548 in a hierarchical triple configuration or is nearby on the sky, but we find such a scenario inadequate to reproduce the observations. The much more likely explanation - but one which still requires more quantitative development - involves macroscopic particles escaping the atmosphere of a slowly disintegrating planet not much larger than Mercury in size. The particles could take the form of micron-sized pyroxene or aluminum oxide dust grains. The planetary surface is hot enough to sublimate and create a high-Z atmosphere; this atmosphere may be loaded with dust via cloud condensation or explosive volcanism. Atmospheric gas escapes the planet via a Parker-type thermal wind, dragging dust grains with it. We infer a mass-loss rate from the observations of order 1 Earth mass / Gyr , with a dust-to-gas ratio possibly of order unity. For our fiducial 0.1 M_Earth planet (twice the mass of Mercury), the evaporation timescale may be ~0.2 Gyr. Smaller mass planets are disfavored because they evaporate still more quickly, as are larger mass planets because they have surface gravities too strong to sustain outflows with the requisite mass-loss rates. The occultation profile evinces an ingress-egress asymmetry that could reflect a comet-like dust tail trailing the planet; we present simulations of such a tail.
  

• Kite, I. Climate change on ancient Mars. II. Exoplanet geodynamics and climate, PhD thesis, University of California, Berkeley. [pdf]
  

• Kite, Gaidos and Manga, Climate instability on tidally locked exoplanets, Astrophysical Journal, 2011. [ More] [pdf] [htm] [Space.com]
  

  Feedbacks that can destabilize the climates of synchronously rotating rocky planets may arise on planets with strong day-night surface temperature contrasts. Earth-like habitable planets maintain stable surface liquid water over geologic time. This requires equilibrium between the temperature-dependent rate of greenhouse-gas consumption by weathering, and greenhouse-gas resupply by other processes. Detected small-radius exoplanets, and anticipated M-dwarf habitable-zone rocky planets, are expected to be in synchronous rotation (tidally locked). In this paper, we investigate two hypothetical feedbacks that can destabilize climate on planets synchronous rotation. (1) If small changes in pressure alter the temperature distribution across a planet's surface such that the weathering rate goes up when the pressure goes down, a runaway positive feedback occurs involving increasing weathering rate near the substellar point, decreasing pressure, and increasing substellar surface temperature. We call this feedback enhanced substellar weathering instability (ESWI). (2) When decreases in pressure increase the fraction of surface area above the melting point (through reduced advective cooling of the substellar point), and the corresponding increase in volume of liquid causes net dissolution of the atmosphere, a further decrease in pressure will occur. This substellar dissolution feedback can also cause a runaway climate shift. We use an idealized energy balance model to map out the conditions under which these instabilities may occur. In this simplified model, the weathering runaway can shrink the habitable zone and cause geologically rapid 10³ - fold atmospheric pressure sits within the habitable zone. Mars may have undergone a weathering runaway in the past. Substellar dissolution is usually a negative feedback or weak positive feedback on changes in atmospheric pressure. It can only cause runaway changes for small, deep oceans and highly soluble atmospheric gases. Both instabilities are suppressed if the atmosphere has a high radiative efficiency. Our results are most relevant for atmospheres that are thin, have low greenhouse-gas radiative efficiency, and have a principal greenhouse gas that is also the main constituent of the atmosphere. ESWI also requires land near the substellar point, and tectonic resurfacing (volcanism, mountain-building) is needed for large jumps in pressure. These results identify a new pathway by which habitable-zone planets can undergo rapid climate shifts and become uninhabitable.

• Kite, Michaels, Rafkin, Dietrich, and Manga, Chaos terrain, storms, and past climate on Mars, JGR-Planets, 2011.
  [ More] [pdf] [dynamic article] [Red Planet Report] ["Research Highlight" in Nature Geoscience]
  

  We model the atmospheric response to a chaos-forming event at Juventae Chasma, north of Valles Marineris, Mars, using the Mars Regional Atmospheric Modeling System (MRAMS). Interactions between lake-driven convergence, topography, and the regional wind field steer lake-induced precipitation to the southwest. Mean snowfall reaches a maximum of 0.9 mm/h water equivalent (peak snowfall 1.7 mm/h water equivalent) on the SW rim of the chasm. More than 80% of vapor released by the lake is trapped in or next to the lake as snow. Radiative effects of the thick cloud cover raise mean plateau surface temperature by up to 18 K locally. We find that the area of maximum modeled precipitation corresponds to the mapped Juventae plateau channel networks. At Echus Chasma, modeled precipitation maxima also correspond to mapped plateau channel networks. This is consistent with the earlier suggestion that Valles Marineris plateau layered deposits and interbedded channel networks result from localized precipitation. However, snowpack thermal modeling shows temperatures below freezing for the 12 mbar CO_2(g) atmosphere used in our MRAMS simulations. This is true even for the most favorable orbital conditions, and whether or not the greenhouse effect of the lake storm is included. Moderately higher CO_2(g) pressures, or non-CO_2(g) greenhouse forcing, is very likely required for melting and plateau channel network formation under a faint young Sun. Required warming is ≤10 K: global temperatures need not be higher than today. In these localized precipitation scenarios, the rest of the planet remains dry.

• Manga, Patel, Dufek and Kite, Wet surface and dense atmosphere on early Mars inferred from the bomb sag at Home Plate, Mars, Geophysical Research Letters, 2011. [ More] [pdf] [htm]
  

  We use the Mars Exploration Rover Spirit observation of a bomb sag produced by an explosive volcanic eruption to infer the atmospheric density at the time of eruption. We performed analogue experiments to determine the relationship between the wetness of the substrate and the velocity and density of impacting clasts and 1) the formation (or not) of bomb sags, 2) the morphology of the impact crater, and 3) the penetration depth of the clast. The downward deflection of beds seen on Mars consistent with water-saturated sediment in the laboratory experiments. Collision angles <20° from vertical are needed to produce bomb sags. From the experiments we infer an impact velocity up to 40 m/s, lower than ejection velocities during phreatic and phreatomagmatic eruptions on Earth. If this velocity represents the terminal subaerial impact velocity, atmospheric density exceeded 0.4 kg/m³ at the time of eruption, much higher than at present.

• Kite, Rafkin, Michaels, Manga, and Dietrich, Localized precipitation and runoff on Mars, JGR-Planets, 2011. [ More] [pdf] [dynamic article] [as reported by "New Scientist"]
  
  We use the Mars Regional Atmospheric Modeling System (MRAMS) to simulate lake storms on Mars, finding that intense localized precipitation will occur for lake size ≥10³ km² . Mars has a low-density atmosphere, so deep convection can be triggered by small amounts of latent heat release. In our reference simulation, the buoyant plume lifts vapor above condensation level, forming a 20 km high optically thick cloud. Ice grains grow to 200μm radius and fall near (or in) the lake at mean rates up to 1.5 mm h^-1 water equivalent (maximum rates up to 6 mm h^-1 water equivalent). Because atmospheric temperatures outside the surface layer are always well below 273 K, supersaturation and condensation begin at low altitudes above lakes on Mars. In contrast to Earth lake-effect storms, lake storms on Mars involve continuous precipitation, and their vertical velocities and plume heights exceed those of tropical thunderstorms on Earth. For lake sizes 10^2.5 to 10^3.5 km, plume vertical velocity scales linearly with lake area. Convection does not reach above the planetary boundary layer for lakes <10³ km² or for atmospheric pressure >O(10²) mbar. Instead, vapor is advected downwind with little cloud formation. Precipitation occurs as snow, and the daytime radiative forcing at the land surface due to plume vapor and storm clouds too small to melt snow directly (<+10 W m^-2). However, if orbital conditions are favorable, then the snow may be seasonally unstable to melting and produce runoff to form channels. We calculate the probability of melting by running thermal models over all possible orbital conditions and weighting their outcomes by probabilities given by long-term integrations of the chaotic diffusion of solar system orbital elements. With this approach, we determine that for an equatorial vapor source, sunlight 15% fainter than at present and snowpack with albedo 0.28 (0.35), melting may occur with 4% (0.1%) probability. This rises to 56% (12%) if the ancient greenhouse effect was modestly (6 K) greater than today.

• Kite, Manga and Gaidos, Geodynamics and rate of volcanism on massive Earth-like planets, Astrophysical Journal, 2009. [ More] [pdf] [htm]
  
  We provide estimates of volcanism versus time for planets with Earth-like composition and masses 0.25-25 M_Earth, as a step toward predicting atmospheric mass on extrasolar rocky planets. Volcanism requires melting of the silicate mantle. We use a thermal evolution model, calibrated against Earth, in combination with standard melting models, to explore the dependence of convection-driven decompression mantle melting on planet mass. We show that (1) volcanism is likely to proceed on massive planets with plate tectonics over the main-sequence lifetime of the parent star; (2) crustal thickness (and melting rate normalized to planet mass) is weakly dependent on planet mass; (3) stagnant lid planets live fast (they have higher rates of melting than their plate tectonic counterparts early in their thermal evolution), but die young (melting shuts down after a few Gyr); (4) plate tectonics may not operate on high-mass planets because of the production of buoyant crust which is difficult to subduct; and (5) melting is necessary but insufficient for efficient volcanic degassing - volatiles partition into the earliest, deepest melts, which may be denser than the residue and sink to the base of the mantle on young, massive planets. Magma must also crystallize at or near the surface, and the pressure of overlying volatiles must be fairly low, if volatiles are to reach the surface. If volcanism is detected in the 10 Gyr old Tau Ceti system, and tidal forcing can be shown to be weak, this would be evidence for plate tectonics.

• Chiang, Kite, Kalas, Graham and Clampin, Fomalhaut's debris disk and planet: Constraining the mass of Fomalhaut b using disk morphology, Astrophysical Journal, 2009. [ More] [pdf]
  
  Fomalhaut's debris disk is gravitationally shaped by a single interior planet. The model is simple, adaptable to other debris disks, and can be extended to accommodate multiple planets. If Fom b is the dominant perturber of the belt, then to produce the observed disk morphology it must have a mass M_pl < 3_MJ, an orbital semimajor axis a_pl > 101.5 AU, and an orbital eccentricity e_pl = 0.11-0.13. These conclusions are independent of Fom b's photometry. To not disrupt the disk, a greater mass for Fom b demands a smaller orbit farther removed from the disk; thus, future astrometric measurement of Fom b's orbit, combined with our model of planet-disk interaction, can be used to determine the mass more precisely. The inner edge of the debris disk at a ~ 133 AU lies at the periphery of Fom b's chaotic zone, and the mean disk eccentricity of e ~ 0.11 is secularly forced by the planet, supporting predictions made prior to the discovery of Fom b. However, previous mass constraints based on disk morphology rely on several oversimplifications. We explain why our constraint is more reliable. It is based on a global model of the disk that is not restricted to the planet's chaotic zone boundary. Moreover, we screen disk parent bodies for dynamical stability over the system age of ~ 100 Myr, and model them separately from their dust grain progeny; the latter's orbits are strongly affected by radiation pressure and their lifetimes are limited to ~ 0.1 Myr by destructive grain-grain collisions. The single planet model predicts that planet and disk orbits be apsidally aligned. Fomalhaut b's nominal space velocity does not bear this out, but the astrometric uncertainties may be large. If the apsidal misalignment proves real, our calculated upper mass limit of 3 MJ still holds. If the orbits are aligned, our model predicts M_pl = 0.5 MJ , a_pl = 115 AU, and e_pl = 0.12. Parent bodies are evacuated from mean-motion resonances with Fom b; these empty resonances are akin to the Kirkwood gaps opened by Jupiter. The belt contains at least 3 M_Earth of solids that are grinding down to dust, their velocity dispersions stirred so strongly by Fom b that collisions are destructive. Such a large mass in solids is consistent with Fom b having formed in situ.

• Kite, Matsuyama, Manga, Perron and Mitrovica, True polar wander driven by late-stage volcanism and the distribution of paleopolar deposits on Mars, Earth and Planetary Science Letters, 2009. [ More] [pdf] [som]
  
  The areal centroids of the youngest polar deposits on Mars are offset from those of adjacent paleopolar deposits by 5-10°. We test the hypothesis that the offset is the result of True Polar Wander (TPW), the motion of the solid surface with respect to the spin axis, caused by a mass redistribution within or on the surface of Mars. In particular, we consider the possibility that TPW is driven by late-stage volcanism during the Late Hesperian to Amazonian. There is observational and qualitative support for this hypothesis: in both north and south, observed offsets lie close to a great circle 90° from Tharsis, as expected for polar wander after Tharsis formed. We calculate the magnitude and direction of TPW produced by mapped late-stage lavas for a range of lithospheric thicknesses, lava thicknesses, eruption histories, and prior polar wander events. We find that if Tharsis formed close to the equator, the stabilizing effect of a fossil rotational bulge located close to the equator leads to predicted TPW of 2°, too small to account for observed offsets. If, however, Tharsis formed far from the equator, late-stage TPW driven by low-latitude, late-stage volcanism would be 6- 33°, similar to that inferred from the location of paleopolar deposits. A volume of 4.4 ± 1.3 x 10¹⁹ kg of young erupted lava can account for the offset of the Dorsa Argentea Formation from the present-day south rotation pole. This volume is consistent with prior mapping-based estimates and would imply a mass release of CO_2(g) by volcanic degassing similar to that in the atmosphere at the present time. The South Polar Layered Deposits are offset from the present rotation pole in a direction that is opposite to the other paleopolar deposits. This can be explained by either a sequential eruption of late-stage lavas, or an additional contribution from a plume beneath Elysium. We predict that significant volcanic activity occurred during the time interval represented by the Basal Unit/Planum Boreum unconformity; Planum Boreum postdates the Promethei Lingula Lobe; and that the north polar deposits span a substantial fraction of Solar System history. If the additional contribution to TPW from plumes small, then we would also predict that Tharsis Montes Formation postdates the Promethei Lingula Lobe of the South Polar Layered Deposits. We conclude with a list of observational tests of the TPW hypothesis.

• Kalas, Graham, Chiang, Fitzgerald, Clampin, Kite, Stapelfeldt, Marois and Krist, Optical images of an exosolar planet 25 light years from Earth, Science, 2008 [ More] [abstract] [#2 Breakthrough of the Year]
  
  Fomalhaut, a bright star 7.7 parsecs (25 light-years) from Earth, harbors a belt of cold dust with a structure consistent with gravitational sculpting by an orbiting planet. Here, we present optical observations of an exoplanet candidate, Fomalhaut b. Fomalhaut b lies about 119 astronomical units (AU) from the star and 18 AU of the dust belt, matching predictions of its location. Hubble Space Telescope observations separated by 1.73 years reveal counterclockwise orbital motion. Dynamical models of the interaction between the planet and the belt indicate that the planet's mass is at most three times that of Jupiter; a higher mass would lead to gravitational disruption of the belt, matching predictions of its location. The flux detected at 0.8 μm is also consistent with that of a planet with mass no greater than a few times that of Jupiter. The brightness at 0.6 μm and the lack of detection at longer wavelengths suggest that the detected flux may include starlight reflected off a circumplanetary disk, with dimension comparable to the orbits of the Galilean satellites. We also observe variability of unknown origin at 0.6 μm.

• Kite and Hindmarsh, Did ice streams shape the largest channels on Mars?, Geophysical Research Letters, 2007. [ More] [pdf]
  
  The largest channels on Mars are the Northwestern Slope Valleys (NSVs) of Tharsis, which have previously been interpreted as the probable erosional trace of catastrophic flooding. It is argued here that ice-streaming within ancient ice sheets emplaced by atmospheric precipitation at high mean obliquity may instead account for these channels, explaining similarities between the region and terrestrial Pleistocene subglacial landscapes. An ice-sheet model shows extensive basal melting in and only in the NSV region, and ice streams which have significant erosive power.

Research interests

Mars. Mars is the only planet whose surface is known to have become uninhabitable. My approach combines geologic data analysis with a hierarchy of models of climate and climate evolution.

Rocky exoplanets. I care deeply about atmosphere-interior exchange and the physical and chemical processes underpinning habitability for rocky exoplanets.

Europa and Enceladus. I maintain a secondary interest in tectonics, surface-interior exchange, and potential habitability for ocean worlds such as Europa and Enceladus.

Extending life beyond Earth.

UChicago Planetary

Public Mars DTMs